A photo-hydrogen-evolving molecular device driving visible-light-induced EDTA-reduction of water into molecular hydrogen.

J Am Chem Soc

Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan.

Published: April 2006

A photo-hydrogen-evolving molecular device made up of a tris(2,2'-bipyridine)ruthenium(II) derivative and a dichloro(2,2'-bipyridine)platinum(II) derivative has been found to serve as the first effective model of a "molecular device" which evolves molecular hydrogen from water in the presence of a sacrificial electron donor (EDTA), under the visible-light illumination.

Download full-text PDF

Source
http://dx.doi.org/10.1021/ja058087hDOI Listing

Publication Analysis

Top Keywords

photo-hydrogen-evolving molecular
8
molecular device
8
molecular hydrogen
8
device driving
4
driving visible-light-induced
4
visible-light-induced edta-reduction
4
edta-reduction water
4
water molecular
4
hydrogen photo-hydrogen-evolving
4
device tris22'-bipyridinerutheniumii
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!