Lattice dynamics of molybdenum at high pressure.

Phys Rev Lett

Earth Science Division, Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550, USA.

Published: March 2006

We have determined the lattice dynamics of molybdenum at high pressure to 37 GPa using high-resolution inelastic x-ray scattering. Over the investigated pressure range, we find a significant decrease in the H-point phonon anomaly. We also present calculations based on density functional theory that accurately predict this pressure dependence. Based on these results, we infer that the likely explanation for the H-point anomaly in molybdenum is strong electron-phonon coupling, which decreases upon compression due to the shift of the Fermi level with respect to the relevant electronic bands.

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http://dx.doi.org/10.1103/PhysRevLett.96.115502DOI Listing

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