Fluctuations of a single step on a vicinal surface are investigated using a discrete model designed to go further in capturing atomistic effects than usually achieved with continuum models. Variants of the model to incorporate the following three types of adatom dynamics are studied: attachment-detachment; periphery (step-edge) diffusion; and terrace diffusion. The dynamic exponent z is determined for each type as well as crossover functions joining three distinct scaling regimes.
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http://dx.doi.org/10.1103/PhysRevE.73.031601 | DOI Listing |
Objective: Countertransference (CT) has been shown to interfere with therapy goals, and its management is crucial to desired treatment outcomes. As a first step, a clinician's awareness of their covert and overt CT reactions is critical to successfully managing CT. Research on CT awareness is scarce, however, mainly because of difficulties in empirically investigating and measuring this construct.
View Article and Find Full Text PDFPLoS One
January 2025
School of Mathematics and Finance, Hunan University of Humanities, Science and Technology, Loudi, China.
During the iterative process of the progressive iterative approximation, it is necessary to calculate the difference between the current interpolation curve and the corresponding data points, known as the adjustment vector. To achieve more precise adjustments of control points, this paper decomposes the adjustment vector into its coordinate components and introduces a weight for each component. By dynamically adjusting these weights, we can accelerate the convergence of iterations and enhance approximation accuracy.
View Article and Find Full Text PDFOtol Neurotol
January 2025
Department of Otorhinolaryngology, Head and Neck Surgery, Inselspital, University Hospital Bern and University of Bern, Bern, Switzerland.
Objective: We aimed to investigate the effect of adding "rapid decelerations" and "vibrations" during a SemontPLUS maneuver on the dynamics of the inner ear and the success rate of canalolithiasis repositioning.
Methods: We used a previously described upscaled (5×) in vitro model of the posterior semicircular canal of the inner ear to analyze the trajectory of a single and clumped surrogate otolith particle (metallic sphere) during a SemontPLUS maneuver (-60 degrees below earth horizontal) on a repositioning chair (TRV). We compared the angular displacement of these particles with and without the application of "vibrations" or "rapid decelerations" using TRV.
Chem Sci
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Soochow University Suzhou Jiangsu 215123 China
Understanding the oxygen reduction reaction (ORR) mechanism and accurately characterizing the reaction interface are essential for improving fuel cell efficiency. We developed an active learning framework combining machine learning force fields and enhanced sampling to explore the dynamics and kinetics of the ORR on Fe-N/C using a fully explicit solvent model. Different possible reaction paths have been explored and the O adsorption process is confirmed as the rate-determining step of the ORR at the Fe-N/C-water interface, which needs to overcome a free energy barrier of 0.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
January 2025
Institut für Chemie und Biochemie, Freie Universität Berlin, Arnimallee 22, 14195 Berlin, Germany.
Since water is both a product and a common reactant impurity in the (partial) methanol oxidation to methyl formate (MeFo) on gold, its effect on the isothermal selectivity to methyl formate was investigated under well-defined single-collision conditions employing pulsed molecular beam experiments and in situ IRAS measurements. Both a flat Au(111) and a stepped Au(332) surface were used as model catalysts to elucidate how water affects the reactivity of low-coordinated step sites as compared to (111) terrace sites employing a range of reaction conditions. The interactions of water with methanol/methoxy as well as with oxygen species are addressed.
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