The concentrations of ozone (O3) and carbon monoxide (CO) on the top of Taishan Mountain were monitored, and the variations and correlation were studied. The results show that the frequency of O3 hourly concentrations more than the first-degree of National Ambient Air Quality Standard(GB-3095-1996, NAAQS) was 15.81%, and the frequency of CO concentrations more than the first-degree of NAAQS was zero. The variation of O3 concentrations appears in a narrow scope, which indicates that there is scarcely influenced by the pollution of industry around. The diurnal variation of the concentrations of O3 and that of CO both present two peaks with the peaks of O3 in the behind of CO, which indicates that the concentration variations of O3 and its precursor CO are primarily controlled by local photochemical reaction process. The daily concentrations of O3 correlated well with CO.
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Nat Commun
January 2025
Shenzhen Key Laboratory of Ecological Remediation and Carbon Sequestration, Institute of Environment and Ecology, Tsinghua Shenzhen International Graduate School, Tsinghua University, Shenzhen, China.
Monitoring methane (CH) emissions from terrestrial ecosystems is essential for assessing the relative contributions of natural and anthropogenic factors leading to climate change and shaping global climate goals. Fires are a significant source of atmospheric CH, with the increasing frequency of megafires amplifying their impact. Global fire emissions exhibit large spatiotemporal variations, making the magnitude and dynamics difficult to characterize accurately.
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Department of Environmental and Biological Sciences, Faculty of Science, Forestry and Technology, University of Eastern Finland, Kuopio, Finland.
Primary and secondary atmospheric pollutants, including carbon monoxide (CO), carbon dioxide (CO), nitrogen oxides (NO), ozone (O), sulphur dioxide (SO) and particulate matter (PM/PM) with associated heavy metals (HMs) and micro- and nanoplastics (MPs/NPs), have the potential to influence and alter interspecific interactions involving insects that are responsible for providing essential ecosystem services (ESs). Given that insects rely on olfactory cues for vital processes such as locating mates, food sources and oviposition sites, volatile organic compounds (VOCs) are of paramount importance in interactions involving insects. While gaseous pollutants reduce the lifespan of individual compounds that act as olfactory cues, gaseous and particulate pollutants can alter their biosynthesis and emission and exert a direct effect on the olfactory system of insects.
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January 2025
Università di Milano-Bicocca, Dipartimento di Scienza dei Materiali, via Cozzi 55, 20125, Milano, ITALY.
Confined single metal atoms in graphene-based materials have proven to be excellent catalysts for several reactions and promising gas sensing systems. However, whether the chemical activity arises from the specific type of metal atom or is a direct consequence of the confinement itself remains unclear. In this work, through a combined density functional theory and experimental surface science study, we address this question by investigating Co and Ni single atoms embedded in graphene (Gr) on a Ni(111) support.
View Article and Find Full Text PDFSmall
January 2025
Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, NM, 87545, USA.
The atomic dispersion of nickel in Ni-N-C catalysts is key for the selective generation of carbon monoxide through the electrochemical carbon dioxide reduction reaction (CORR). Herein, the study reports a highly selective, atomically dispersed Ni-N-C catalyst with reduced Ni loading compared to previous reports. Extensive materials characterization fails to detect Ni crystalline phases, reveals the highest concentration of atomically dispersed Ni metal, and confirms the presence of the proposed Ni-N active site at this reduced loading.
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January 2025
The Toxikon Consortium, 1950 West Polk St, 7th Floor, Chicago, IL, 60612, USA.
Carbon monoxide (CO) poisoning continues to result in hospitalization and mortality. We sought to analyze risk factors associated with inpatient admission for CO poisoning. Retrospective study of the US National Inpatient Sample (NIS) database.
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