It is shown that if there exists a supercompact cardinal then every set of reals, which is an element of L(R), is the projection of a weakly homogeneous tree. As a consequence of this theorem and recent work of Martin and Steel [Martin, D. A. & Steel, J. R. (1988) Proc. Natl. Acad. Sci. USA 85, 6582-6586], it follows that (if there is a supercompact cardinal) every set of reals in L(R) is determined.
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http://dx.doi.org/10.1073/pnas.85.18.6587 | DOI Listing |
J Clin Med
January 2025
Department of Radiology, Radiotherapy and Nuclear Medicine, National Medical Institute of the Ministry of the Interior and Administration, 02-507 Warsaw, Poland.
: This study aimed to determine if MRI features can distinguish between spinal infections caused by pyogenic bacteria and Mycobacterium tuberculosis. : Patients underwent an MRI of the thoracolumbar spine with and without contrast. Three blinded observers assessed the images, using statistical tests for analysis.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
University of Amsterdam Van 't Hoff Institute for Molecular Sciences: Universiteit van Amsterdam Van 't Hoff Institute for Molecular Sciences, HIMS, NETHERLANDS, KINGDOM OF THE.
The complexity of allosteric enzymatic regulation continues to inspire synthetic chemists seeking to emulate interconnected biological systems. In this work, a Pt2L4 cage capable of catalyzing the cyclization reaction of an alkynoic tosyl amide is orthogonally coupled to a diacid-catalyzed carbodiimide-hydration cycle. This new Pt-catalyzed cyclization reaction is demonstrated to exhibit electronic regulation by inclusion of different guest effectors.
View Article and Find Full Text PDFSci Rep
January 2025
Northwest Oilfield Company, SINOPEC, Ürümqi, 830011, China.
Deep oil reservoirs are becoming increasingly significant fields of hydrocarbon exploration in recent decades. Hydrothermal fluid flow is deemed as a potentially crucial factor affecting the occurrence of deep oil reservoirs, such as enhancing porosity/permeability of reservoirs, accelerating oil generation and thermal cracking, and modifying organic properties of crude oils. Understanding the interplay between hydrothermal fluids and crude oils would provide useful constraints for reconstructing hydrocarbon accumulation processes and predicting the distribution patterns of crude oils.
View Article and Find Full Text PDFMolecules
December 2024
Laboratoire de Chimie de Coordination, CNRS, Toulouse-INP, Université de Toulouse, 31000 Toulouse, France.
In recent years, there has been growing interest in the development of greener alternatives to traditional reagents used in carbon-carbon coupling reactions, particularly in response to environmental concerns. The commonly used aryl halides, despite being highly reactive in the Suzuki-Miyaura coupling (SMC), pose significant environmental risks. As a result, research has shifted towards exploring the use of phenols, which are widely accessible and environmentally benign.
View Article and Find Full Text PDFEur Phys J E Soft Matter
January 2025
Soft Matter Science and Engineering (SIMM), ESPCI Paris, PSL University, Sorbonne Université, CNRS, Rue Vauquelin, 75005, Paris, France.
The creep behavior of an amorphous poly(etherimide) polymer is investigated in the vicinity of its glass transition in a weakly non linear regime where the acceleration of the creep response is driven by local configurational rearrangements. From the time shifts of the creep compliance curves under stresses from 1 to 15 MPa and in the temperature range between and , where is the glass transition temperature, we determine a macroscopic acceleration factor. The macroscopic acceleration is shown to vary as temperature with , where is the macroscopic stress and Y is a decreasing function of compliance.
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