A coordination pi-pi framework exhibits spontaneous magnetization.

Chem Commun (Camb)

Department of Chemistry, Center of Nanoscience and Nanotechnology, National Chung-Hsing University, Taichung 402, Taiwan (Republic of China).

Published: March 2006

AI Article Synopsis

  • The pi-pi scaffolding framework is a one-dimensional chain structure made up of alternating Delta- and Lambda-iron(II) chiral units.
  • This structure, represented as [Fe(II)(Delta)Fe(II)(Lambda)(ox)2(phen)2]n, exhibits spontaneous magnetization.
  • Below 10 K, it produces noticeable hysteresis loops, indicating interesting magnetic behavior.

Article Abstract

A pi-pi scaffolding framework that was assembled as a one-dimensional chain structure comprising alternating Delta- and Lambda-iron(II) chiral building units, [Fe(II)(Delta)Fe(II)(Lambda)(ox)2(phen)2]n, reveals spontaneous magnetization that gives rise to pronounced hysteresis loops below 10 K.

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http://dx.doi.org/10.1039/b515681eDOI Listing

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