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Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect. | LitMetric
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Thiacalix[3]pyridine produces a stable mononuclear rhodium(II) complex with mutual Jahn-Teller effect.

Rika Tanaka Hamazawa Takanori Nishioka Isamu Kinoshita Takeji Takui Ryoko Santo Akio Ichimura

Dalton Trans

Department of Molecular Materials Science, Graduate School of Science, Osaka City University, Sumuyoshi-ku, Japan.

Published: March 2006

Thiacalix[3]pyridine (Py3S3) consists of pyridines and bridging sulfur atoms producing a stable octahedral mononuclear Rh(II) complex [Rh(II)(Py3S3)2]2+ showing mutual Jahn-Teller effect, a metal based reversible redox couple of Rh(III/II) at 0.02 V vs. SCE and a g(perpendicular) > g(||) relationship in EPR measurements.

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http://dx.doi.org/10.1039/b515926aDOI Listing

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