Reaction of RLi with lead(II) bromide affords the diaryl lead(II) compounds PbR2 (R1 = 2,4,6-triphenylphenyl, 1; R2 = 2,6-bis(1'-naphthyl)phenyl, 2), which have monomeric, carbene-like structures with bent two-coordinate Pb(II) centers.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/b513401c | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
-heterocyclic carbene and cyclic (alkyl)(amino)carbene adducts of plumbanes and plumbylenes.
Dalton Trans
September 2022
Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany.
-acid/base adducts of -heterocyclic carbenes (NHCs) and the cyclic (alkyl)(amino)carbene cAAC (1-(2,6-di-iso-propylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene) with selected lead(II) and lead(IV) compounds are presented. The reaction of the NHCs MeIm (1,3,4,5-tetramethyl-imidazolin-2-ylidene), iPrIm (1,3-di-isopropyl-4,5-dimethyl-imidazolin-2-ylidene), DippIm (1,3-bis-(2,6-di-isopropylphenyl)-imidazolin-2-ylidene) and cAAC (1-(2,6-di-iso-propylphenyl)-3,3,5,5-tetramethyl-pyrrolidin-2-ylidene) with PbI yielded the NHC-containing plumbylenes NHC·PbI (NHC = MeIm (1), iPrIm (2), DippIm (3) and cAAC·PbI (4)). Using the Pb(IV) compound PbClPh, the plumbane adducts NHC·PbClPh (NHC = MeIm (5), iPrIm (6), DippIm (7)) and cAAC·PbClPh (8)) were isolated in high yields.
View Article and Find Full Text PDFSyntheses and structures of new diaryl lead(II) compounds PbR2 (1, R = 2,4,6-triphenylphenyl; 2, R = 2,6-bis(1-naphthyl)phenyl).
Chem Commun (Camb)
January 2006
Department of Chemistry, University of Georgia, Athens, 30602-2556, USA.
Reaction of RLi with lead(II) bromide affords the diaryl lead(II) compounds PbR2 (R1 = 2,4,6-triphenylphenyl, 1; R2 = 2,6-bis(1'-naphthyl)phenyl, 2), which have monomeric, carbene-like structures with bent two-coordinate Pb(II) centers.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!