We present a new measurement of the s-wave scattering length a of spin-polarized helium atoms in the 2(3)S1 metastable state. Using two-photon photoassociation spectroscopy and dark resonances, we measure the energy E(nu)=14= -91.35+/- 0.06 MHz of the least-bound state nu = 14 in the interaction potential of the two atoms. We deduce a value of a=7.512+/-0.005 nm, which is at least 100 times more precise than the best previous determinations and is in disagreement with some of them. This experiment also demonstrates the possibility to create exotic molecules binding two metastable atoms with a lifetime of the order of 1 micros.
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