The phase behavior of AfmN(BN2AN2)B(1-fmN) multiblock copolymer melts is studied within the weak segregation theory. The interplay between ordering on different length scales is shown to cause dramatic changes both in the ordered phase symmetry and periodicity upon small variation of the architectural parameters of the macromolecules. Phase diagrams are presented in the (f,chiN) plane (chi is the Flory-Huggins parameter) for various values of the architecture parameters n and m. Near the critical surface, i.e., for (f-0.5)2<<1, such nonconventional cubic phases as the face-centered cubic (FCC), simple cubic (SC), (double) gyroid, and the so-called BCC(2) (single gyroid) are found to be stable. The lamellar morphology is shown to be replaced by BCC2, FCC, or SC (depending on the structural parameters) as the most stable low-temperature phase.
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J Am Chem Soc
December 2024
Polymer Synthesis Laboratory, Laboratory, Chemistry Program, KAUST Catalysis Center, Physical Sciences and Engineering Division, King Abdullah University of Science and Technology (KAUST), Thuwal 23955, Saudi Arabia.
Uniform sugar-functionalized polyesters combine the benefits of sugar's structural diversity, biocompatibility, and biodegradability with precise postfunctionalization capabilities, making them a highly valuable class of materials with extensive application potential. However, the irregular placement of hydroxyl groups has limited the synthesis of these polyesters. Here, we present the first platform for uniform sugar-functionalized polyesters via regioselective ring-opening copolymerizations (ROCOPs) of allopyranoside anhydrosugar epoxide (, derived from d-glucose) with cyclic anhydrides, followed by complete selective deprotection.
View Article and Find Full Text PDFAdv Healthc Mater
December 2024
Polymer Science, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 3, Groningen, 9747 AG, The Netherlands.
Melt electrowriting (MEW) is a powerful additive manufacturing technique to produce tissue engineering scaffolds. Despite its strength, it is limited by a small number of processable polymers. Therefore, to broaden the library of materials for MEW, we investigated the printability of poly(ethylene oxide terephthalate)-poly(butylene terephthalate) (PEOT-PBT), a thermoplastic elastomer.
View Article and Find Full Text PDFMacromol Biosci
November 2024
Department of Chemistry, Paderborn University, Warburger Str. 100, 33098, Paderborn, Germany.
A strategy for multifunctional biosurfaces exploiting multiblock copolymers and the antipolyelectrolyte effect is reported. Combining a polyzwitterionic/antifouling and a polycationic/antibacterial block with a central anchoring block for attachment to titanium oxide surfaces affords surface coatings that exhibit antifouling properties against proteins and allow for surface regeneration by clearing adhering proteins by employing a salt washing step. The surfaces also kill bacteria by contact killing, which is aided by a nonfouling block.
View Article and Find Full Text PDFJ Am Chem Soc
December 2024
Department of Chemistry, The University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, United States.
The synthetic toolbox for stimuli-responsive polymers has broadened to include many tunable variables, making these materials applicable in diverse technologies. However, unraveling the key composition-structure-function relationships to facilitate ground-up design remains a challenge due to the inherent dispersity in sequence and conformations for synthetic polymers. We here present a systematic study of these relationships using a model system of copolymers with a thermoresponsive (-isopropylacrylamide) backbone in addition to metal-chelating (acrylic acid) and hydrophobic structural comonomers and evaluate their efficiency at isolating technologically critical lanthanide ions.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
October 2024
Key Laboratory of Biobased Polymer Materials, College of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, 266042, China.
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