Dicarbonyl-stabilised diazo functionality is tolerated during alkene cross-metathesis using Grubbs' catalyst, but undergoes subsequent tandem carbonyl ylide formation-intramolecular 1,3-dipolar cycloaddition on addition of catalytic Rh2(OAc)4 in a one-pot operation.
Download full-text PDF |
Source |
---|---|
http://dx.doi.org/10.1039/b515943a | DOI Listing |
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!