Message: file_get_contents(https://...@gmail.com&api_key=61f08fa0b96a73de8c900d749fcb997acc09): Failed to open stream: HTTP request failed! HTTP/1.1 429 Too Many Requests
* The synthesized nickel and copper nanorods have diameters of 250 nm and 130 nm, respectively, with lengths of about 2.5 microm for nickel and 480 nm for copper, and their shape can be altered by changing the solvent used.
* Nickel oxalate nanorods exhibit an antiferromagnetic transition at 34 K, while copper oxalate nanorods show temperature-independent paramagnetism.
Article Abstract
Nanorods of nickel and copper oxalate have been synthesized by the reverse micellar route. Powder X-ray diffraction studies and thermo gravimetric analysis confirms the formation of monophasic NiC2O4 x 2H2O and CuC2O4 x H2O. Transmission electron microscopy shows that the as prepared nanorods of nickel and copper have diameter of 250 nm and 130 nm while the length is of the order of 2.5 microm and 480 nm respectively. The aspect ratio of the nanorods could be modified by changing the solvent. The nickel oxalate nanorods appear very smooth with uniform length while the copper oxalate nanorods appear to be corrugated. Nickel oxalate dihydrate nanorods show an antiferromagnetic transition at T(N) = 34 K while the copper based nanorods show temperature independent paramagnetism.
