[reaction: see text] The mechanism of the reaction of azafullerene radical C(59)N(*) with diphenylmethane and 9-methyl-9H-fluorene has been investigated. The primary and secondary kinetic isotope effects provide strong evidence for a stepwise mechanism in which the hydrogen-atom abstraction is the rate-determining step.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1021/jo051838d | DOI Listing |
Publication Analysis
Top Keywords
reaction aza[60]fullerene
4
aza[60]fullerene radical
4
radical diphenylmethanes
4
diphenylmethanes fluorenes
4
fluorenes mechanistic
4
mechanistic approach
4
approach [reaction
4
[reaction text]
4
text] mechanism
4
mechanism reaction
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!