Structural properties of polymer brushes on nanopatterned surfaces in good solvent have been determined by computer simulations. Scaling relations for the brush height and brush width are proposed. The properties of the central part of the patterned brush remain constant as long as the pattern is wider than a few times the brush height. The results agree qualitatively with recent AFM experiments, but some quantitative differences call for a reassessment of experimental procedures.
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http://dx.doi.org/10.1021/nl051611y | DOI Listing |
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