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Cross-sensitivities of electrochemical detectors used to monitor worker exposures to airborne contaminants: false positive responses in the absence of target analytes. | LitMetric

Cross-sensitivities of electrochemical detectors used to monitor worker exposures to airborne contaminants: false positive responses in the absence of target analytes.

J Environ Monit

Université du Québec (UQTR), correspondence address at the National Research Council (NRC) of Canada, Fire Research Program, Bldg M59 1200 Montreal Road, Ottawa, CanadaK1A 0R6.

Published: January 2006

AI Article Synopsis

  • Electrochemical detectors should ideally respond to specific airborne chemicals in a way that corresponds directly to their concentration, without interference from other substances.
  • Although manufacturers list known cross-sensitivities, users have reported unexpected interferences, highlighting potential gaps in product information.
  • Testing revealed that different models of detectors had varying responses to certain chemicals, indicating that undocumented cross-sensitivities exist among the different devices.

Article Abstract

Ideally, the response of electrochemical detectors is proportional to the concentration of targeted airborne chemicals and is not be affected by concomitantly present substances. Manufacturers provide a limited list of cross-sensitivities but end-users have anecdotally reported unexpected interferences by other substances. Electrochemical detectors designed to measure airborne levels of CO, H(2)S, NO, NO(2), or SO(2), were challenged with potentially interfering substances in the absence of target analytes. Cross-sensitivities undocumented by the manufacturers were observed and were found to vary between different models of instruments for the same challenge chemical.

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Source
http://dx.doi.org/10.1039/b510084dDOI Listing

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