We report the discovery of a new class of an electric field-driven bulk phase transition due solely to dipolar interactions in a suspension under the action of a uniform ac field where the effects of other competing forces are suppressed. This transition appears after the well-known chain-column formation and causes the uniform suspension of columns to rearrange into a cellular pattern consisting of particle-free domains surrounded by particle-rich walls. Interestingly, the characteristic size of these domains scales linearly with the interelectrode spacing and remains insensitive to the size of the particles.
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http://dx.doi.org/10.1103/PhysRevLett.95.258301 | DOI Listing |
ACS Appl Mater Interfaces
December 2018
School of Physics , University College Dublin, Belfield 4 , Dublin 4 , Ireland.
Relaxor ferroelectrics exhibit a range of interesting material behavior, including high electromechanical response, polarization rotations, as well as temperature and electric field-driven phase transitions. The origin of this unusual functional behavior remains elusive due to limited knowledge on polarization dynamics at the nanoscale. Piezoresponse force microscopy and associated switching spectroscopy provide access to local electromechanical properties on the micro- and nanoscale, which can help to address some of these gaps in our knowledge.
View Article and Find Full Text PDFAdv Struct Chem Imaging
March 2017
X-ray Science Division, Argonne National Laboratory, Lemont, IL 60439 USA.
X-ray diffraction imaging is rapidly emerging as a powerful technique by which one can capture the local structure of crystalline materials at the nano- and meso-scale. Here, we present investigations of the dynamic structure of epitaxial monodomain BiFeO thin-films using a novel full-field Bragg diffraction imaging modality. By taking advantage of the depth penetration of hard X-rays and their exquisite sensitivity to the atomic structure, we imaged in situ and in operando, the electric field-driven structural responses of buried BiFeO epitaxial thin-films in micro-capacitor devices, with sub-100 nm lateral resolution.
View Article and Find Full Text PDFPhys Rev Lett
December 2005
The Levich Institute, The City College of New York, 140th Street & Convent Avenue, New York, New York 10031, USA.
We report the discovery of a new class of an electric field-driven bulk phase transition due solely to dipolar interactions in a suspension under the action of a uniform ac field where the effects of other competing forces are suppressed. This transition appears after the well-known chain-column formation and causes the uniform suspension of columns to rearrange into a cellular pattern consisting of particle-free domains surrounded by particle-rich walls. Interestingly, the characteristic size of these domains scales linearly with the interelectrode spacing and remains insensitive to the size of the particles.
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