A luminescent supramolecular chiral Au16 ring with 4.822 nm perimeter that self-assembled from a tetrameric array of achiral Au2 units is described. Intra- and intermolecular Au...Au interactions play an important role in directing its chiral self-assembly.
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Self-assembly of a Au16 ring via metal-metal bonding interactions.
Chem Asian J
May 2015
Laboratory for Self-Assembly Chemistry, Department of Chemistry, Renmin University of China, Beijing 100872 (P.R. China).
Metal-metal bonding interactions have been employed as an efficient strategy to generate a number of unique gold(I) metallo-macrocycles with fascinating functions. The self-assembly, crystal structure and emission property of novel nest-like tetramer 1(4), namely, {[Au(4) (μ-dppm)2 (μ-dctp(2-))](BF(4))(2)}(4)⋅(CH(3)CN)(2) (dppm=bis(diphenylphosphino)methane, dctp(2-) =N,N'-bis(dicarbodithioate)-2,11-diaza[3.3]paracyclophane) is reported.
View Article and Find Full Text PDFA chiral luminescent Au16 ring self-assembled from achiral components.
J Am Chem Soc
December 2005
State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, People's Republic of China.
A luminescent supramolecular chiral Au16 ring with 4.822 nm perimeter that self-assembled from a tetrameric array of achiral Au2 units is described. Intra- and intermolecular Au.
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