The comparison of the photochemical properties of three aromatic and five aliphatic amino acids and three dipeptides was carried out using 212.8 nm laser irradiation and high performance liquid chromatography. The photochemical sensitivity, photolysis quantum yield and quantum yield of peptide bond scission were determined. Two-photon absorption coefficients of solvent (liquid water) and cell windows material (fused silica) at lambda = 212.8 nm were established.

Download full-text PDF

Source
http://dx.doi.org/10.1016/1011-1344(92)85028-sDOI Listing

Publication Analysis

Top Keywords

2128 laser
8
aromatic aliphatic
8
aliphatic amino
8
amino acids
8
quantum yield
8
laser photolysis
4
photolysis aromatic
4
acids peptides
4
peptides comparison
4
comparison photochemical
4

Similar Publications

Carbonate fluorapatite coatings on phillipsite represent a significant sink of phosphorus in abyssal plains of the western Pacific Ocean.

Proc Natl Acad Sci U S A

February 2025

Department of Earth System Sciences, Center for Earth System Research and Sustainability, University of Hamburg, Hamburg 20146, Germany.

As an essential micronutrient, phosphorus plays a key role in oceanic biogeochemistry, with its cycling intimately connected to the global carbon cycle and climate change. Authigenic carbonate fluorapatite (CFA) has been suggested to represent a significant phosphorus sink in the deep ocean, but its formation mechanisms in oceanic low-productivity settings remain poorly constrained. Applying X-ray absorption near edge structure, transmission electron microscopy, and laser ablation inductively coupled plasma mass spectrometer analyses, we report a unique mineral assemblage where CFA crystals coat phillipsite in abyssal sediments of the East Mariana Basin and the Philippine Sea.

View Article and Find Full Text PDF

Fused silica with surface structures has potential applications in microfluidic, aerospace and other fields. To fabricate structures with high dimensional accuracy and surface quality is of paramount importance. However, it is indeed a challenge to strike a balance between accuracy and efficiency at the same time.

View Article and Find Full Text PDF

Adjunctive treatment of periodontitis lacks solutions which allow for enough time for wound healing in the periodontal pockets by avoiding fast re-colonization. Such a solution might be an antibiotic-containing formulation with a controlled release over a period of weeks. Here, a recently described minocycline-containing approach is qualified for further clinical development by focusing on proof-of-concept, systemic burden, resistance development, and degradation studies.

View Article and Find Full Text PDF

Femtosecond laser pulses are currently regarded as an emerging and promising tool for processing wide bandgap dielectric materials across a variety of high-end applications, although the associated physical phenomena are not yet fully understood. To address these challenges, we propose an original, fully analytical model combined with Two Temperatures Model (TTM) formalism. The model is applied to describe the interaction of fs laser pulses with a typical dielectric target (e.

View Article and Find Full Text PDF

Resonant Cell-Based 1 Photoacoustic Gas Analyzer Immune to Light Power Fluctuation and Frequency Mismatch.

Anal Chem

October 2024

Department of Precision Instruments, State Key Laboratory of Precision Measurement Technology and Instruments, Tsinghua University, Beijing 100084, China.

To overcome the light power fluctuation and frequency mismatch in photoacoustic spectroscopy (PAS), we proposed a self-corrected 1-only resonant cell-based PAS (1-RCPAS) gas analyzer. Based on the theoretical analysis of the 1 signal, a signal processing algorithm considering laser power-current nonlinearity is proposed. The 1-only algorithm is well-tailored for the resonant systems, requiring no time-division multiplexing.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!