Determination of carbendazim residues in fruit juices by liquid chromatography-tandem mass spectrometry.

Food Addit Contam

Faculty of Technology and Metallurgy - Analytical Chemistry, Belgrade, Serbia and Montenegro.

Published: November 2005

In this paper a rapid optimized method for routine analysis of carbendazim residues in fruit juices is reported. The procedure is based on matrix solid-phase dispersion (MSPD) with diatomaceous earth and analysis of the extract by liquid chromatography-tandem mass spectrometry, with electrospray ionization (LC-ESI-MS/MS). In the method optimization, finding of the optimal pH for the extraction of carbendazim from juice was particularly critical. Significant matrix effects were observed, but could be eliminated using matrix-matched standards. High recoveries (82-102%), good repeatability (RSD

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http://dx.doi.org/10.1080/02652030500352863DOI Listing

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