In this paper a rapid optimized method for routine analysis of carbendazim residues in fruit juices is reported. The procedure is based on matrix solid-phase dispersion (MSPD) with diatomaceous earth and analysis of the extract by liquid chromatography-tandem mass spectrometry, with electrospray ionization (LC-ESI-MS/MS). In the method optimization, finding of the optimal pH for the extraction of carbendazim from juice was particularly critical. Significant matrix effects were observed, but could be eliminated using matrix-matched standards. High recoveries (82-102%), good repeatability (RSD
Download full-text PDF
Source
http://dx.doi.org/10.1080/02652030500352863 DOI Listing Publication Analysis
Top Keywords
Polymers (Basel)
January 2025
Key Laboratory of Radiopharmaceuticals, Ministry of Education, College of Chemistry, Beijing Normal University, Beijing 100875, China.
The highly selective and sensitive determination of pesticide residues in food is critical for human health protection. Herein, the specific selectivity of molecularly imprinted polymers (MIPs) was proposed to construct an electrochemical sensor for the detection of carbendazim (CBD), one of the famous broad-spectrum fungicides, by combining with the synergistic effect of bioelectrocatalysis and nanocomposites. Gold nanoparticle-reduced graphene oxide (AuNP-rGO) composites were electrodeposited on a polished glassy carbon electrode (GCE).
View Article and Find Full Text PDFJ Chromatogr A
January 2025
Institute of Business Scientific, Henan Academy of Sciences, Wenhua Road #87, Zhengzhou, Henan, 450003, PR China. Electronic address:
A flat membrane-based liquid-phase microextraction (FM-LPME) method was developed for the first time to simultaneously separate and extract basic and acidic pesticide analytes from the same sample. Using carbendazim and pirimicarb as representative basic pesticides, along with bromacil, diflubenzuron and 1,2-dibenzoyl-1‑tert-butylhydrazine (RH-5849) as representative acidic pesticides, the performance of FM-LPME for the extraction of these model pesticides has been optimised individually. Under optimal extraction conditions, the developed FM-LPME-LC-MS/MS method exhibited excellent linearity, with R values exceeding 0.
View Article and Find Full Text PDFEnviron Pollut
December 2024
Department of Microbiology, College of Life Sciences, Nanjing Agricultural University, Nanjing, Jiangsu, PR China. Electronic address:
The proliferation of weeds, pests, and plant diseases in crop cultivation has driven the increased application of herbicide lactofen, insecticide acetamiprid, and fungicide carbendazim, contributing to environmental pollution. Microorganisms are requently employed to remove pesticide residues from the environment. However, Liquid bacterial agents encounter difficulties in transportation and preservation during application and the current immobilized bacterial agents have a single degradation function.
View Article and Find Full Text PDFFood Chem
March 2025
School of Chemistry and Chemical Engineering, Yancheng Institute of Technology, Yancheng, China. Electronic address:
Carbendazim abuse in agriculture can lead to the residue in water and food, which may bring about adverse effects to human's health. In this study, we report the solvothermal synthesis of free-metal single TT-COF with one-step strategy and the TT-COF-based electrochemical sensor is fabricated for the further sensing of carbendazim. The TT-COF possesses high surface area, excellent conductivity and outstanding electrocatalytic activity.
View Article and Find Full Text PDFFood Chem X
December 2024
State Key Laboratory of Green Pesticide, Key Laboratory of Green Pesticide and Agricultural Bioengineering, Ministry of Education, Center for R&D of Fine Chemicals of Guizhou University, Guiyang 550025, China.
This study aims to apply multivariate analysis algorithms for modeling the same spectra, for simultaneous determination of pymetrozine and carbendazim residues in apple. To mitigate the impact of competitive adsorption, SERS spectra are obtained from mixed solutions of pymetrozine and carbendazim at varying concentration ratios, which are then utilized for modeling. Results suggest that the PLSR model based on full-band SNV processed spectra shows the best performance for predicting pymetrozine and carbendazim contents, with R2 of 0.
View Article and Find Full Text PDFEnter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!