Di-mu-chloro-bis[bis[2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole-kappa2C2',N]iridium(III)] dichloromethane disolvate.

Acta Crystallogr C

Department of Chemistry, Wuhan University, Wuhan 430072, People's Republic of China.

Published: December 2005

In the title compound, [Ir2(C16H13N2O3)4Cl2].2CH2Cl2, the two Ir atoms, 3.7075 (6) angstroms apart, are bridged by two Cl atoms which straddle a twofold axis of rotation through the two Ir atoms. Each Ir centre resides in a distorted octahedral environment completed by two chelating 2,5-bis(4-methoxyphenyl)-1,3,4-oxadiazole ligands, with trans-N-N and cis-C-C dispositions. In the stacking structure, there are two types of hydrogen bonds, involving the methoxy substituent, an N atom of the oxadiazole ring and the dichloromethane solvent molecules.

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http://dx.doi.org/10.1107/S0108270105031951DOI Listing

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In the title compound, [Ir2(C16H13N2O3)4Cl2].2CH2Cl2, the two Ir atoms, 3.7075 (6) angstroms apart, are bridged by two Cl atoms which straddle a twofold axis of rotation through the two Ir atoms.

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