[reaction: see text] We have developed a facile and efficient tritium labeling method using a Pd/C-HTO-H2 system. This method can provide multitritium-labeled compounds in highly diluted HTO under T2 gas-free conditions, and is environmentally benign since purification by silica gel column chromatography is not necessary, which causes a large quantity of radioactive waste such as silica gel and eluent.
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http://dx.doi.org/10.1021/jo0517545 | DOI Listing |
Dalton Trans
January 2025
Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan, Shanxi 030024, China.
BiVO is considered as one of the important candidate materials for photoelectrochemical water splitting technology. However, the low efficiency of charge separation and poor kinetics of water oxidation limit its performance in PEC water splitting. In this work, a BiVO/MIL-53(FeNiCo) photoanode was constructed by a facile hydrothermal deposition method, exhibiting excellent water oxidation ability under AM 1.
View Article and Find Full Text PDFCurr Org Synth
January 2025
Stem Cells Technology Research Center, Shiraz University of Medical Sciences, Shiraz, Iran.
Introduction: The development of efficient and sustainable catalytic methodolo-gies has garnered considerable attention in contemporary organic synthesis.
Methods: Herein, we present a novel approach employing the Cu@DPP-SPION catalyst for the synthesis of ethyl 4-(aryl)-6-methyl-2-thioxo-1,2,3,4-tetrahydropyrimidine-5-carboxylate derivatives. This versatile catalytic system incorporates copper nanoparticles supported on 4-(1H-imidazo[4,5-f][1,10]phenanthrolin-2-yl)benzoic acid-functionalized superparamagnetic iron oxide nanoparticles (SPIONs).
ACS Energy Lett
January 2025
Department of Physics, Technical University of Denmark, Kongens Lynby 2800, Denmark.
We discuss the challenges associated with achieving high energy efficiency in electrochemical ammonia synthesis at near-ambient conditions. The current Li-mediated process has a theoretical maximum energy efficiency of ∼28%, since Li deposition gives rise to a very large effective overpotential. As a starting point toward finding electrocatalysts with lower effective overpotentials, we show that one reason why Li and alkaline earth metals work as N reduction electrocatalysts at ambient conditions is that the thermal elemental processes, N dissociation and NH desorption, are both facile at room temperature for these metals.
View Article and Find Full Text PDFJ Am Chem Soc
January 2025
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China.
Quaternary carbon centers are widespread structural motifs, thus representing extensive interest in organic synthesis. We describe here an efficient nickel-catalyzed intermolecular, -selective arylation of minimally functionalized alkenes with stable organoborons, affording a broad range of cyclic or acyclic quaternary carbon centers under mild conditions. The utilization of the diimine ligand is critical for high reactivity and chemoselectivity.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Department of Optoelectronic Information of Science and Engineering, School of Science, Jiangsu University of Science and Technology, Zhenjiang 212100, China.
Reasonable design of hydrogen evolution reaction (HER) electrocatalysts with low Pt loading and excellent catalytic performance is a key challenge in finding efficient and cost attractive catalysts. Pt with its unique d-electrons provides new opportunities for the development of HER catalysts when it forms compounds with highly earth-abundant C. Herein, we focused on designing highly efficient catalysts composed of Pt and C elements using first-principles structure search simulations, identifying four stability PtC monolayers.
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