Experiments were conducted to determine the effects of composting or simple addition of compost to the mineralization of n-hexadecane, pyrene and benzo(a)pyrene in soil. Soil (contaminated or clean) was composted with maple leaves and alfalfa. Samples from different composting phases were spiked with radiolabeled and cold n-hexadecane, pyrene or benzo(a)pyrene, placed in aerated microcosms at different temperatures, and monitored for mineralization. It was determined that neither composting nor the addition of compost had any effect on n-alkane or benzo(a)pyrene mineralization. In contrast, the pyrene mineralization rate increased dramatically with the amount of time that soil had been composted. Highest pyrene mineralization rates and extents (more than 60% after 20 days) were obtained when pyrene was in contact with composted soil from the curing stage. Neither thermophiles (55 degrees C) nor fungi were responsible for pyrene mineralization.
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http://dx.doi.org/10.1007/s10532-005-4217-8 | DOI Listing |
Langmuir
January 2025
International Iberian Nanotechnology Laboratory, 4715-330 Braga, Portugal.
This study investigates the effect of different linkers and solvents on the immobilization of DNA probes on graphene surfaces, which are crucial for developing high-performance biosensors. Quartz crystal microbalance with dissipation (QCM-D) measurements were used to characterize in situ and real-time the immobilization of ssDNA and hybridization efficiency on model graphene surfaces. The DNA probes immobilization kinetics and thermodynamics were systematically investigated for all the pairings between three bifunctional linkers─1-pyrenebutyric acid succinimidyl ester (PBSE), Fluorenylmethylsuccinimidyl carbonate (FSC), and Acridine Orange (AO) succinimidyl ester─and three organic solvents (DMF, DMSO, and 10% DMF/ethanol).
View Article and Find Full Text PDFTalanta
April 2025
Department of Chemistry, Lorestan University, Khoramabad, Iran.
A significant challenge in membrane production is the need for affordable materials that provide high efficiency for their designated applications. Employing recycled materials in membrane manufacturing is viewed as a promising solution to tackle this challenge. In this work, a superwettable polyethylene terephthalate membrane modified with cobalt zeolitic imidazolate framework (PET/Co ZIF) is prepared for the first time from recycled plastic mineral water bottles and used to extract polycyclic aromatic hydrocarbons (PAHs) from aqueous samples followed by high-performance liquid chromatography with UV detection (HPLC-UV).
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
December 2024
School of Biology and Biological Engineering, South China University of Technology, Guangzhou, 510006, China.
Toxics
November 2024
Department of Bioengineering, King Fahd University of Petroleum and Minerals, Dhahran 31261, Saudi Arabia.
J Hazard Mater
December 2024
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China.
This study aimed to enhance the efficiency of SBES in remediating polycyclic aromatic hydrocarbon (PAH)-contaminated soils by modifying the anode with laccase. The experiment involved four SBES anodes: a carbon nanotube-modified anode (CNT), a free laccase-modified anode (Lac), a gelatin-encapsulated laccase-modified anode (Lac-Gel), and a CaCO sustained-release microsphere-loaded laccase-modified (CaCO-SMs@Laccase) anode (Lac-SMs). The CaCO-SMs@Laccase notably extended the active period of laccase, with laccase activity in the Lac-SMs measured at 1.
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