AI Article Synopsis
- A method is outlined for creating complex cyclopentane compounds using a Brook rearrangement.
- The reaction involves a cyclization process that promotes stereoselectivity, ensuring specific configurations of the product.
- The key reactants in this process include tert-butyldimethylsilyl-1,3-dithianyllithium and homochiral 1,4-bis-epoxides.
Article Abstract
[reactions: see text] A concise synthesis of highly functionalized cyclopentane derivatives via a Brook rearrangement mediated stereoselective linchpin cyclization reaction involving tert-butyldimethylsilyl-1,3-dithianyllithium and homochiral 1,4-bis-epoxides is described.
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| http://dx.doi.org/10.1021/ol052009h | DOI Listing |
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