The replacement of common organic solvents by room-temperature ionic liquids (RTILs) is a topical subject in both academia and industry. In the last decades, the number of applications for RTILs has followed an exponential curve and spilled over the boundaries of chemistry. Still, one of the main drawbacks of these compounds is their difficult access. The present ultrasound-assisted method affords a general and easy access to a large variety of room-temperature ionic liquids.
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http://dx.doi.org/10.1016/j.ultsonch.2005.09.001 | DOI Listing |
J Chem Phys
January 2025
Department of Materials Science and Engineering, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8552, Japan.
The liquid/liquid interfaces of room-temperature ionic liquids (RTILs) play a pivotal role in chemical reactions owing to their characteristic microscopic structure, yet the structure of hydrophobic liquid/RTIL interfaces remains unclear. We studied the structure at the liquid/liquid interfaces of carbon tetrachloride (CCl4) and 1-alkyl-3-methylimidazolium bis(trifluoromethanesulfonyl)amide ([Cnmim][TFSA]; n = 4 and 8) RTILs using infrared-visible sum frequency generation (SFG) vibrational spectroscopy. A comparison of the SFG spectra of the CCl4/RTIL and air/RTIL interfaces revealed that the solvation of the alkyl chains of the [Cnmim]+ cations by CCl4 reduces the number of gauche defects in the alkyl chain and the interface number density of the cation at the CCl4 interface.
View Article and Find Full Text PDFWaste Manag
December 2024
College of Environmental Science and Engineering and Key Laboratory of Environmental Biology and Pollution Control (Ministry of Education), Hunan University, Changsha 410082, PR China.
With the exponential growth of global photovoltaic (PV) installed capacity, the quantity of discarded PV modules continues to rise. This study innovatively explored the sustainable recovery and utilization of raw materials from discarded solar panels, focusing on the transformation of recycled silicon into microporous silica nanoparticles (MSN). Low toxic organic solvent ethyl acetate (EA) was for the first time utilized to reduce the viscosity of ethylene-vinyl acetate (EVA) and facilitated its removal.
View Article and Find Full Text PDFChem Mater
December 2024
Center for Nanophase Materials Sciences, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831, United States.
Solid polymer electrolytes have yet to achieve the desired ionic conductivity (>1 mS/cm) near room temperature required for many applications. This target implies the need to reduce the effective energy barriers for ion transport in polymer electrolytes to around 20 kJ/mol. In this work, we combine information extracted from existing experimental results with theoretical calculations to provide insights into ion transport in single-ion conductors (SICs) with a focus on lithium ion SICs.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Tianjin Key Laboratory for Photoelectric Materials and Devices, School of Materials Science and Engineering, Tianjin University of Technology, Tianjin 300384, P.R. China.
Beta-AlO-based solid-state sodium metal batteries are some of the best options for large-scale energy storage systems because of their high energy density, high-level safety, and low cost. Nevertheless, their room-/low-temperature operation remains challenging due to low ionic conductivity of Beta-AlO electrolyte and weak solid-solid contact of the Na/Beta-AlO interface. Herein, an integrated strategy was developed via electrolyte optimization and interface regulation, in which Cu as a stabilizing agent was incorporated into Beta-AlO to improve density and ionic conductivity and the InS interface layer was introduced between the Na anode and solid electrolyte to induce the in situ formation of a mixed conductive layer (Na-In alloy and NaS).
View Article and Find Full Text PDFJ Phys Chem B
December 2024
Department of Chemistry, Eszterházy Károly Catholic University, Leányka utca 12, H-3300 Eger, Hungary.
In this work, we carry out a systematic computer simulation investigation of the single particle dynamics at the free surface of imidazolium-based room temperature ionic liquids by applying intrinsic surface analysis. Besides assessing the effect of the potential model and temperature, we focus in particular on the effect of changing the anion type, and, hence, their shape and size. Further, we also address the role of the length of the cation alkyl chains, known to protrude into the vapor phase, on the surface dynamics of the ions.
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