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Isolation of an intermediate in the insertion of a carbodiimide into a boron-aryl bond. | LitMetric
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Isolation of an intermediate in the insertion of a carbodiimide into a boron-aryl bond.

Nicholas J Hill Jennifer A Moore Michael Findlater Alan H Cowley

Chem Commun (Camb)

Department of Chemistry and Biochemistry, University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, USA.

Published: November 2005

A 1 : 1 Lewis acid-base complex between CyN=C=NCy and PhBCl2 has been isolated and structurally characterized, heating of which in refluxing toluene results in the amidinate, [PhC{NCy}2]BCl2; the overall reaction has been modeled by DFT calculations.

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 Source
http://dx.doi.org/10.1039/b511080gDOI Listing

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