The behaviour of concrete at elevated temperatures is important for an assessment of integrity (strength and durability) of structures exposed to a high-temperature environment, in applications such as fire exposure, smelting plants and nuclear installations. In modelling terms, a coupled thermomechanical analysis represents a generalization of the computational mechanics of fracture and damage. Here, we develop a fully coupled anisotropic thermomechanical damage model for concrete under high stress and transient temperature, with emphasis on the adherence of the model to the laws of thermodynamics. Specific analytical results are given, deduced from thermodynamics, of a novel interpretation on specific heat, evolution of entropy and the identification of the complete anisotropic, thermomechanical damage surface. The model is also shown to be stable in a computational sense, and to satisfy the laws of thermodynamics.
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http://dx.doi.org/10.1098/rsta.2005.1589 | DOI Listing |
Polymers (Basel)
January 2025
Institute of Chemistry and Chemical Technology, Faculty of Natural Sciences and Technology, Riga Technical University, P. Valdena 3, LV-1048 Riga, Latvia.
Despite the impressive properties of additively manufactured products, their inherent anisotropy is a crucial challenge for polymeric parts made via fused filament fabrication (FFF). This study compared the tensile, thermophysical, smoke density, and toxicity characteristics of Ultem 9085 (a blend of polyetherimide and polycarbonate) for samples printed in various orientations (X, Y, and Z). The results revealed that mechanical properties, such as elastic modulus and tensile strength, significantly differed from the Z printing orientation, particularly in the X and Y printing layer orientations.
View Article and Find Full Text PDFJ Colloid Interface Sci
April 2025
School of Physics and Astronomy, The University of Edinburgh, Peter Guthrie Tait Road, Edinburgh EH9 3FD, UK; Department of Physics, University of Gothenburg, SE-41296 Gothenburg, Sweden; University of Münster, Institute of Physical Chemistry, Corrensstr. 28/30, 48149 Münster, Germany. Electronic address:
Hypothesis: Ellipsoidal particles confined at liquid interfaces exhibit complex self-assembly due to quadrupolar capillary interactions, favouring either tip-to-tip or side-to-side configurations. However, predicting and controlling which structure forms remains challenging. We hypothesize that introducing a polymer-based soft shell around the particles will modulate these capillary interactions, providing a means to tune the preferred self-assembly configuration based on particle geometry and shell properties.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Customized Manufacturing R&D Department, Korea Institute of Industrial Technology, Siheung 15014, Republic of Korea.
The presence of AlCuFe particles, formed due to Fe impurities in Al-Zn-Mg-Cu alloys, significantly impacts mechanical properties and formability, which is crucial for the use of these alloys in the automotive and aerospace industries. In this study, we prepared Al-Zn-Mg-Cu-based alloy sheets with large (LF), small (SF), and no (NF) AlCuFe particles to explore their effects on recrystallization and mechanical behavior. These sheets were fabricated using controlled cooling rates and subsequent thermo-mechanical processing.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2024
Department of Chemical and Biological Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States.
Multimaterial 3-D printing (3DP) of isotropic (IsoE) and liquid crystalline elastomers (LCE) yields spatially programmed elements that undergo a cuboidal shape transformation upon heating. The thermomechanical deformation of 3DP elements is determined by the geometry and extent of the isotropic and anisotropic regions. The synthesis and experimental characterization of the 3DP elements are complemented by finite element analysis (FEA).
View Article and Find Full Text PDFAdv Mater
December 2024
Advanced Materials Laboratory, Sandia National Laboratories, Albuquerque, NM, 87106, USA.
Liquid crystalline elastomers (LCEs) are anisotropic soft materials capable of large dimensional changes when subjected to a stimulus. The magnitude and directionality of the stimuli-induced thermomechanical response is associated with the alignment of the LCE. Recent reports detail the preparation of LCEs by additive manufacturing (AM) techniques, predominately using direct ink write printing.
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