We present a Monte Carlo study of a lattice gas driven out of equilibrium by a local hopping bias. Sites can be empty or occupied by one of two types of particles, which are distinguished by their response to the hopping bias. All particles interact via excluded volume and a nearest-neighbor attractive force. The main result is a phase diagram with three phases: a homogeneous phase and two distinct ordered phases. Continuous boundaries separate the homogeneous phase from the ordered phases, and a first-order line separates the two ordered phases. The three lines merge in a nonequilibrium bicritical point.
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http://dx.doi.org/10.1103/PhysRevE.72.036127 | DOI Listing |
Sci Rep
January 2025
Department of Physics, Faculty of Science, Islamic University of Madinah, Al-Jamia, Madinah, 42351, Saudi Arabia.
This study focuses on the synthesis of a novel Cerium-Magnesium (CeO-MgO) binary oxide nanomaterials by a simple co-precipitation process and used to remove harmful pollutants such as Cr(VI), Cu(II), and F. The morphology, phase, crystallite size, thermal stability, functional groups, surface area, and porosity of the synthesized nanomaterial were determined by using XRD, SEM, FTIR, TGA/DTA, and BET studies. The prepared nanomaterials showed adsorption selectivity of Cu(II) ≈ F> Cr(VI) with a high adsorption capacity of 84.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
Homi Bhabha National Institute, Anushakti Nagar, Mumbai 400094, India.
Introduction of non-DLVO forces by nonionic surfactants brings about fascinating changes in the phase behavior of silica nanosuspensions. We show here that alterations in the interaction and wetting properties of negatively charged silica nanoparticles (Ludox® LS) in the presence of polyethylene oxide-polypropylene oxide-polyethylene oxide-based triblock copolymers called Pluronics lead to the formation of stable o/w Pickering emulsions and interparticle attraction-induced thermoresponsive liquid-liquid phase separations. The results make interesting comparisons with those reported for Ludox® TM nanosuspensions comprising larger silica nanoparticles.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
School of Environment and Architecture, University of Shanghai for Science and Technology, Shanghai 200093, China.
The bioaccessibility of cadmium (Cd) and lead (Pb) in the gastrointestinal tract is crucial for health risk assessments of contaminated soils. However, variability in In vitro analytical conditions and soil properties introduces bias and uncertainty in predictions. This study employed three in vitro methods to measure Cd and Pb bioaccessibility during the gastric and gastrointestinal phases, using soil samples incubated for one year.
View Article and Find Full Text PDFJ Phys Condens Matter
January 2025
School of Physical Sciences, Indian Association for the Cultivation of Science, 2A & B Raja S C Mullick Road, Kolkata 700032, INDIA, Kolkata, 700032, INDIA.
The breaking of inversion symmetry combined with spin-orbit coupling, can give rise to intrigu- ing quantum phases and collective excitations. Here, we report systematic temperature dependent Raman scattering and theoretical calculations of phonon modes across the inversion symmetry- breaking structural transitions in a quasi-one-dimensional compound (TaSe4)3I. Our investigation revealed the emergence of three additional Raman-active modes in Raman spectra of the low- temperature (LT) non-centrosymmetric (NC) structure of the material.
View Article and Find Full Text PDFBMC Chem
January 2025
Nuclear Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy Authority, P.O. 13759, Cairo, Egypt.
In this work, selenium (IV) ions were adsorbed from aqueous solutions by the strongly basic anion exchange resin Amberlite IRA-400. The morphology of the resin before and after Se(IV) sorption was investigated using different techniques such as energy dispersive X-ray spectroscopy (EDX), Fourier transform infrared spectroscopy (FTIR), and scanning electron microscopy (SEM). To determine the ideal sorption conditions, a batch approach was used to examine the variables affecting Se(IV) sorption performance, including pH, shaking time, adsorbent dosage, initial metal ion concentration, and temperature.
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