Quantum observable homotopy tracking control.

J Chem Phys

Department of Chemistry, Princeton University, Princeton, New Jersey 08544-1009, USA.

Published: October 2005

This paper presents a new tracking method where the target observable O(s,T) at the final dynamical time T follows a predefined track P(s) with respect to a homotopy tracking variable s>or=0. The procedure calculates the series of control fields E(s,t) required to accomplish observable homotopy tracking by solving a first-order differential equation in s for the evolution of the control field. Controls produced by this technique render the desired track for all s without encountering field singularities. This paper also extends the technique to the case where the field-free Hamiltonian and dipole moment operator change with s in order to explore the control of new physical systems along the track. Several simulations are presented illustrating the various uses for this quantum tracking control technique.

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http://dx.doi.org/10.1063/1.2042456DOI Listing

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