In this work we demonstrate the feasibility of electric-field tuning of the plasmonic spectrum of a novel gold nanodot array in a liquid crystal matrix. As opposed to previously reported microscopically observed near-field spectral tuning of individual gold nanoparticles, this system exhibits macroscopic far-field spectral tuning. The nanodot-liquid crystal matrix also displays strong anisotropic absorption characteristics, which can be effectively described as a collective ensemble within a composite matrix in the lateral dimension and a group of noninteracting individual particles in the normal direction. The effective medium model and the Mie theory are employed to describe the experimental results.
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http://dx.doi.org/10.1021/nl0513535 | DOI Listing |
Molecules
January 2025
Departamento de Ingeniería Química y de Materiales, Facultad de Ciencias Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain.
Water pollution, resulting from industrial effluents, agricultural runoff, and pharmaceutical residues, poses serious threats to ecosystems and human health, highlighting the need for innovative approaches to effective remediation, particularly for non-biodegradable emerging pollutants. This research work explores the influence of shape-controlled nanocrystalline titanium dioxide (TiO NC), synthesized by a simple hydrothermal method, on the photodegradation efficiency of three different classes of emerging environmental pollutants: phenol, pesticides (methomyl), and drugs (sodium diclofenac). Experiments were conducted to assess the influence of the water matrix on treatment efficiency by using ultrapure water and stormwater (basic) collected from an urban drainage system as matrices.
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January 2025
Department of Engineering Science, The University of Electro-Communications, Chofu 182-8585, Tokyo, Japan.
A new compound [Y(sq)(HO)] (Y-sq; sq = squarate (CO)) was prepared and structurally characterized. Since the RE-sq family (RE = Y, Dy, Yb, Lu) gave isostructural crystals, the objective of this study is to explore the effects of diamagnetic dilution on the SIM behavior through systematic investigation and comparison of diamagnetically diluted and undiluted forms. The 1%-Diluted Dy compounds, Dy@Y-sq and Dy@Lu-sq, showed AC magnetic susceptibility peaks without any DC bias field (), whereas undiluted Dy-sq showed no AC out-of-phase response under the same conditions.
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January 2025
School of Mechanical and Electrical Engineering, Hainan University, Haikou 570228, China.
The phononic crystals composed of soft materials have received extensive attention owing to the extraordinary behavior when undergoing large deformations, making it possible to provide tunable band gaps actively. However, the inverse designs of them mainly rely on the gradient-driven or gradient-free optimization schemes, which require sensitivity analysis or cause time-consuming, lacking intelligence and flexibility. To this end, a deep learning-based framework composed of a conditional variational autoencoder and multilayer perceptron is proposed to discover the mapping relation from the band gaps to the topology layout applied with prestress.
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January 2025
Research Center of Digital Oral Science and Technology, College of Oral Medicine, Taipei Medical University, Taipei 110-301, Taiwan.
Bulk metallic glasses (i.e., BMGs) have attracted a lot of research and development interest due to their unique properties.
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January 2025
State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, No. 127, Youyi Road (West), Xi'an 710072, China.
In this work, the high cycle fatigue behavior and tensile properties of Ti-Al-Mo-Cr-V-Nb-Zr-Sn titanium alloy at room temperature with a basketweave structure and bimodal structure were studied. The results show that the fatigue strength of the basketweave structure is higher, while the balance of strength and plasticity of the bimodal microstructure is better. However, the fatigue performance of the bimodal microstructure is unstable due to the bilinear phenomenon of the S-N curve.
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