A thermally and air stable O-donor, iridium-methoxo complex is reported that undergoes stoichiometric, intermolecular C-H activation of benzene with co-generation of methanol and the iridium-phenyl complex.
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CH activation with an O-donor iridium-methoxo complex.
J Am Chem Soc
October 2005
Donald P. and Katherine B. Loker Hydrocarbon Research Institute and Department of Chemistry, University of Southern California, Los Angeles, CA 90089, USA.
A thermally and air stable O-donor, iridium-methoxo complex is reported that undergoes stoichiometric, intermolecular C-H activation of benzene with co-generation of methanol and the iridium-phenyl complex.
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