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Boron-mediated stereoselective syntheses of gamma,gamma-disubstituted allenamides. | LitMetric

Boron-mediated stereoselective syntheses of gamma,gamma-disubstituted allenamides.

J Org Chem

Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.

Published: October 2005

Propargylic boranes generated by lithiation of optically active N-propargyloxazolidinones undergo reaction with a range of aldehydes to produce gamma,gamma-disubstituted allenamides with good diastereoselectivity.

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Source
http://dx.doi.org/10.1021/jo051385cDOI Listing

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