A new method, passive flux meter (PFM), has been developed and field-tested for simultaneously measuring contaminant and groundwater fluxes in the saturated zone at hazardous waste sites. The PFM approach uses a sorptive permeable medium placed in either a borehole or monitoring well to intercept contaminated groundwater and release "resident" tracers. The sorbent pack is placed in a groundwater flow field for a specified exposure time and then recovered for extraction and analysis. By quantifying the mass fraction of resident tracers lost and the mass of contaminant sorbed, groundwater and contaminant fluxes are calculated. Here, we assessed the performance of PFMs at the Canadian Forces Base Borden field site in Ontario, Canada. Two field tests were conducted under imposed groundwater flow fields: (1) radial flow to a well and (2) linear flow in a test channel confined by sheet pile walls on three sides. Both tests demonstrate that the local fluxes measured by PFM and averaged overthe screen interval were within 15% of imposed groundwaterflow and within 30% of measured contaminant mass flux. Patterns in depth variations in groundwater and contaminant fluxes, determined by the PFM approach, allow for site characterization at a higher spatial resolution. These results support the PMF method as a potential innovative alternative for measuring groundwater and contaminant fluxes in screened wells.
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http://dx.doi.org/10.1021/es050074g | DOI Listing |
Lett Appl Microbiol
January 2025
Egg and Poultry Production Safety Research Unit, U.S. Department of Agriculture, Agricultural Research Service, U.S. National Poultry Research Center, Athens, GA, U.S.A.
Salmonella is an enteric pathogenic bacterium in mammals that thrives in sewage, soil, and aquatic environments because of its wide ecological adaptability. The spread of Salmonella infection is associated with a lack of clean water, poor hygiene, and poor sanitation in developing countries. However, the input of Salmonella-contaminated surface water and groundwater in the environmental dissemination of antimicrobial-resistant Salmonella is obscure outside developed countries.
View Article and Find Full Text PDFSci Total Environ
January 2025
Department of Geosciences & Natural Resource Management, Geology, University of Copenhagen, Denmark.
Due to increasing plastic production, the continuous release of primary and secondary nanoplastic particles (NPs, <1 μm) has become an emerging contaminant in terrestrial environments. The fate and transport of NPs in subsurface environments remain poorly understood, largely due to the complex interplay of mineralogical, chemical, biological, and morphological heterogeneity. This study examines interactions between abundant subsurface minerals and NPs under controlled water chemistry (1 mM KCl, pH 5.
View Article and Find Full Text PDFSci Total Environ
January 2025
Korea Mine Rehabilitation and Mineral Resources Corporation, Wonju, Gangwon-do 26464, Republic of Korea.
Tracing the sources of each contaminant and its geochemical reactions requires a variety of geochemical tools. In this study, chemical compositions and isotopic ratios of O-H, Mo, and Zn were utilized to identify the sources and geochemical reactions of water, As, Mo, and Zn in the seepage from a mine tailings dump. The distinct chemical compositions observed between the seepage and monitoring well, along with the O-H isotopic ratios, suggested that the seepage originated from creek water rather than nearby groundwater, which was supported by a large seasonal variation of δMo in both the seepage and creek.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
College of Water Sciences, Beijing Normal University, Beijing 100875, China; Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing Normal University, Beijing 100875, China.
Light nonaqueous-phase liquids (LNAPLs) are the main source of organic pollution in soil and groundwater environments. The capillary zone, with varying moisture contents, is the last barrier against the infiltration of LNAPL pollutants into groundwater and plays an important role in their migration and transformation. However, the effect and mechanism of the moisture content in the capillary zone on LNAPL pollutant migration are still unclear.
View Article and Find Full Text PDFJ Hazard Mater
January 2025
Department of Civil and Environmental Engineering, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Republic of Korea; Department of Environmental Engineering, Graduate School, Konkuk University, 120 Neungdong-ro, Gwangjin-gu, Seoul 05029, Republic of Korea. Electronic address:
The synthesis of coal bottom ash-induced zeolite (Si-Al material) has been widely reported; however, the selective recovery of the three main elements, viz., Si, Al, and Fe, from coal bottom ash for the synthesis of reactive adsorbents has not yet been reported. In this study, we separated the magnetic and non-magnetic fractions of coal bottom ash to selectively recover Fe and Si-Al for synthesizing nanoscale zero-valent iron@zeolite (NZVI@ZBA) composites with uniform formation of Fe(0) nanoparticles on the ZBA surface.
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