Synchrotron x-ray diffraction is used to compare the misfit strain and composition in a self-organized nanowire array in an InAs/GaSb superlattice with InSb interfacial bonds to a planar InAs/GaSb superlattice with GaAs interfacial bonds. It is found that the morphological instability that occurs in the nanowire array results from the large misfit strain that the InSb interfacial bonds have in the nanowire array. Based on this result, we propose that tailoring the type of interfacial bonds during the epitaxial growth of III-V semiconductor films provides a novel approach for producing the technologically important morphological instability in anomalously thin layers.
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http://dx.doi.org/10.1103/PhysRevLett.95.096104 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
Shandong University of Science and Technology, Institute of Carbon Neutrality, College of Chemical and Biological Engineering, No 579 Qianwangang Road, Huangdao District, 266590, Qingdao, CHINA.
Traditionally weak buried interaction without customized chemical bonding always goes against the formation of high-quality perovskite film that highly determines the efficiency and stability of perovskite solar cells. To address this issue, herein, we propose a bimolecular nucleophilic substitution reaction (SN2) driving strategy to idealize the robust buried interface by simultaneously decorating underlying substrate and functionalizing [PbX6]4- octahedral framework with iodoacetamide and thiol molecules, respectively. Theoretical and experimental results demonstrate that a strong SN2 reaction between exposed halogen and thiol group in two molecules occurs, which not only benefits the reinforcement of buried adhesion, but also triggers target-point-oriented crystallization, synergistically upgrading the upper perovskite film quality and accelerating interfacial charge extraction-transfer behavior.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Southern University of Science and Technology, Department of Mechanical and Energy Engineering, 1088 Xueyuan Blvd, Nanshan District, 518055, Shenzhen, CHINA.
The escape of organic cations over time from defective perovskite interface leads to non-stoichiometric terminals, significantly affecting the stability of perovskite solar cells (PSCs). How to stabilize the interface composition under environmental stress remains a grand challenge. To address this issue, we utilize thiol-functionalized particles as a "seed" and conduct in situ polymerization of 2,2,3,4,4,4-hexafluorobutyl methacrylate (HFMA) as a "root" at the bottom of the perovskite layer.
View Article and Find Full Text PDFNanoscale
January 2025
School of Chemistry and Chemical Engineering, North Minzu University, Yinchuan 750021, PR China.
Despite the potential to significantly enhance the economic viability of biomass-based platforms through the selective conversion of glycerol to 1,3-dihydroxyacetone (DHA), a formidable challenge persists in simultaneously achieving high catalytic activity and stability along this reaction pathway. Herein, we have devised a strategic approach to manipulate the interfacial integration within composite catalysts to address the performance trade-off. Through the modulation of the composite process involving a bio-templated porous ZSM-5 zeolite platform (bZ) and an Au/CuZnO catalyst, three distinct interfacial bonding modes were achieved: physical milling, encapsulation by zeolite, and growth on zeolite.
View Article and Find Full Text PDFJ Dent Sci
January 2025
Department of Conservative Dentistry and Periodontology, University Hospital, LMU Munich, Munich, Germany.
Background/purpose: Although clinical studies have suggested a link between non-axial forces and reduced longevity of cervical restorations, the underlying mechanisms require further numerical investigation. This in-silico study employed a cohesive zone model (CZM) to investigate interfacial damage in a cervical restoration subjected to different load directions.
Materials And Methods: A plane strain model of a maxillary premolar was established, with a wedge-shaped buccal cervical restoration.
Heliyon
January 2025
A. K. M. Masud, Department of Industrial and Production Engineering (IPE), Bangladesh University of Engineering and Technology (BUET), Dhaka-1000, Bangladesh.
Polymers have been ruling the packaging industry for decades due to their versatility, easy manufacturability, and low cost. The overuse of non-biodegradable plastics in food packaging has become a serious environmental concern. Multi-walled carbon nanotube (MWCNT) reinforced nanocomposites have exceptional electrical, thermal, and mechanical properties.
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