The sterically protected dithiadiazolyl radical (F3C)3C6H2CNSSN. (1) crystallises in two polymorphs: 1alpha, comprised of monomeric units and 1beta, containing a mixture of both pi*-pi* dimers and S = (1/2) monomers; whilst both polymorphs exhibit similar structure-directing motifs, the variation in packing leads to different magnetic behaviour.
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http://dx.doi.org/10.1039/b508371k | DOI Listing |
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