2-Methyl-(1Z,3E)-butadiene-1,3,4-tricarboxylic acid, "isoprenetricarboxylic acid".

J Org Chem

Laboratory of Applied Mass Spectrometry, National Heart, Lung, and Blood Institute, Bethesda, Maryland 20892, USA.

Published: September 2005

[reaction: see text] The synthesis of the title compound 7 from ethyl glyoxylate and dimethyl and diethyl beta-methylglutaconate is described along with its physical properties that suggest its inability to assume a cis-dienoid structure due to steric hindrance between the methyl and carboxyl groups.

Download full-text PDF

Source
http://dx.doi.org/10.1021/jo0507892DOI Listing

Publication Analysis

Top Keywords

2-methyl-1z3e-butadiene-134-tricarboxylic acid
4
acid "isoprenetricarboxylic
4
"isoprenetricarboxylic acid"
4
acid" [reaction
4
[reaction text]
4
text] synthesis
4
synthesis title
4
title compound
4
compound ethyl
4
ethyl glyoxylate
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!