It is generally believed that the old quantum theory, as presented by Niels Bohr in 1913, fails when applied to few electron systems, such as the H(2) molecule. Here, we find previously undescribed solutions within the Bohr theory that describe the potential energy curve for the lowest singlet and triplet states of H(2) about as well as the early wave mechanical treatment of Heitler and London. We also develop an interpolation scheme that substantially improves the agreement with the exact ground-state potential curve of H(2) and provides a good description of more complicated molecules such as LiH, Li(2), BeH, and He(2).
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http://dx.doi.org/10.1073/pnas.0505778102 | DOI Listing |
Ber Wiss
December 2020
Director Emeritus, Niels Bohr Archive, Copenhagen.
The Danish physicist Niels Bohr is best known for two major achievements: first, his model of the quantum atom, published in 1913, for which he received the Nobel Prize in 1922; and second, the "Copenhagen interpretation" of quantum mechanics developed together with colleagues at his institute in the latter half of the twenties. Having turned his institute toward nuclear physics, making it a pioneer institution in this emerging field, Bohr escaped from Nazi-occupied Denmark in 1943. Learning in England about the advanced state of the secret project to develop an atomic bomb, which Bohr had so far considered impracticable in a foreseeable future, he agreed to join the project.
View Article and Find Full Text PDFNature
June 2019
Department of Applied Physics, Yale University, New Haven, CT, USA.
In quantum physics, measurements can fundamentally yield discrete and random results. Emblematic of this feature is Bohr's 1913 proposal of quantum jumps between two discrete energy levels of an atom. Experimentally, quantum jumps were first observed in an atomic ion driven by a weak deterministic force while under strong continuous energy measurement.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
November 2013
Department of Chemistry, University of Siegen, 57068 Siegen (Germany); Tsinghua University Beijing, Beijing 100084 (China).
In the fall of 1913 Niels Bohr formulated his atomic models at the age of 27. This Essay traces Bohr's fundamental reasoning regarding atomic structure and spectra, the periodic table of the elements, and chemical bonding. His enduring insights and superseded suppositions are also discussed.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
August 2005
Department of Chemistry, Princeton University, Princeton, NJ 08544, USA.
It is generally believed that the old quantum theory, as presented by Niels Bohr in 1913, fails when applied to few electron systems, such as the H(2) molecule. Here, we find previously undescribed solutions within the Bohr theory that describe the potential energy curve for the lowest singlet and triplet states of H(2) about as well as the early wave mechanical treatment of Heitler and London. We also develop an interpolation scheme that substantially improves the agreement with the exact ground-state potential curve of H(2) and provides a good description of more complicated molecules such as LiH, Li(2), BeH, and He(2).
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