We fabricate microchannels in fused silica by femtosecond laser irradiation followed by etching in diluted hydrofluoric acid. We show a dramatic dependence of the etch rate on the laser polarization, spanning 2 orders of magnitude. We establish the existence of an energy-per-pulse threshold at which etching of the laser-modified zones becomes highly polarization selective. The enhanced selective etching is due to long-range, periodic, polarization-dependent nanostructures formed in the laser-modified material.
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http://dx.doi.org/10.1364/ol.30.001867 | DOI Listing |
Talanta
January 2025
DSM-Firmenich, Kogle Allé 4, 2970, Hørsholm, Denmark.
The development and validation of an accurate, selective, and eco-friendly capillary zone electrophoretic detection (CZE) method has been presented for concurrent measurement of inorganic and organic anions including chloride, sulfate, formic acid, citric acid, acetic acid, phosphate, and glutamic acid in Human Milk Oligosaccharides (HMOs) for the first time. An electrolyte composed of an aqueous solution of benzoic acid, 16.38 mM; l-histidine, 24.
View Article and Find Full Text PDFACS Omega
January 2025
Instituto de Física de São Carlos, Universidade de São Paulo, São Carlos, SP 13560-970, Brasil.
Direct laser writing (DLW) has been recognized as a unique technique for three-dimensional (3D) prototyping with resolution beyond the diffraction limit. One trend in DLW technologies is the use of polymers, given their favorable mechanical properties and optical quality, rendering them promising for the next generation of nonlinear photonic devices. However, absorptive properties that facilitate DLW processes may also hinder the performance of polymers as all-optical devices.
View Article and Find Full Text PDFWe demonstrate experimentally an efficient terahertz emitter that consists of a 20 µm thick layer of LiNbO clamped between a fused silica substrate and a Si semicone. A focused laser beam from an ultrafast optical oscillator propagates in the LiNbO layer and emits a Cherenkov cone of terahertz radiation to the Si semicone. The radiation is totally internally reflected by the semicone's convex surface and escapes the semicone through its base as a collimated beam.
View Article and Find Full Text PDFLangmuir
January 2025
Department of Chemistry, The University of Utah, Salt Lake City, Utah 84112, United States.
Slip flow, a fluid flow enhanced in comparison to that calculated using continuum equations, has been reported for many nanopores, mostly those with hydrophobic surfaces. We investigated the flow of water, hexane, and methanol through hydrophilic nanopores in silica colloidal crystals. Three silica sphere sizes were used to prepare the crystals: 150 ± 30, 500 ± 40, and 1500 ± 100 nm.
View Article and Find Full Text PDFAnal Chim Acta
February 2025
Department of Pharmaceutical Chemistry, Medical University of Gdansk, Hallera 107, 80-416, Gdansk, Poland.
Background: Benzodiazepine abuse remains a significant public health concern. Current sample preparation methods for benzodiazepine analysis from human serum often involve complex procedures that require large sample volumes and extensive organic solvent use. To address these limitations, this study presents a novel and efficient sample preparation method utilizing 3D-printed sorbent devices.
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