Dipolar interactions in liquids and linear dielectric relaxation spectroscopy.

Phys Rev E Stat Nonlin Soft Matter Phys

Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, 60-179 Pozńan, Poland.

Published: May 2005

Linear dielectric relaxation studies performed on two isotropic liquids composed of the molecules of the same moment of inertia and a quite different polarity: C10H21-O-Ph-COO-Ph-CN (the dipole moment of about 5 D) and C10H21-O-Ph-OOC-Ph-CN (2.5 D) showed that, at given temperature, the relaxation times corresponding to the rotation around the short axis of the two kinds of molecules coincide to each other, regardless the polarity of the molecules and their abilities to accomplish dipolar aggregation. The studies allow one to estimate the lifetime of the intermolecular aggregates due to the dipolar interactions in liquids as no longer than 0.1 ns.

Download full-text PDF

Source
http://dx.doi.org/10.1103/PhysRevE.71.052701DOI Listing

Publication Analysis

Top Keywords

dipolar interactions
8
interactions liquids
8
linear dielectric
8
dielectric relaxation
8
liquids linear
4
relaxation spectroscopy
4
spectroscopy linear
4
relaxation studies
4
studies performed
4
performed isotropic
4

Similar Publications

Efficient Orthogonal Spin Labeling of Proteins via Aldehyde Cyclization for Pulsed Dipolar EPR Distance Measurements.

J Am Chem Soc

December 2024

State Key Laboratory of Elemento-organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China.

Pulsed dipolar electron paramagnetic resonance (PD-EPR) measurement is a powerful technique for characterizing the interactions and conformational changes of biomolecules. The extraction of these distance restraints from PD-EPR experiments relies on manipulation of spin-spin pairs. The orthogonal spin labeling approach offers unique advantages by providing multiple distances between different spin-spin pairs.

View Article and Find Full Text PDF

Creating and Deleting a Single Dipolar Skyrmion by Surface Spin Twists.

Nano Lett

December 2024

Anhui Province Key Laboratory of Low-Energy Quantum Materials and Devices, High Magnetic Field Laboratory, HFIPS, Chinese Academy of Sciences, Hefei, 230031, China.

We report deterministic operations on single dipolar skyrmions confined in nanostructured cuboids by using in-plane currents. We achieve highly reversible writing and deleting of skyrmions in a simple cuboid without any artificial defects or pinning sites. The current-induced creation of skyrmions is well-understood through the spin-transfer torque acting on surface spin twists of the spontaneous 3D ferromagnetic state, caused by the magnetic dipole-dipole interaction of the uniaxial FeSn magnet with a low-quality factor.

View Article and Find Full Text PDF

This work illustrates a physico-chemical study of the structural, dynamic, and transport properties of electrolytes made of LiTFSI solutions in sulphoxide and sulphone solvent mixtures. Experimental measurements, by Raman and NMR spectroscopies, as well as electrochemical impedance spectroscopy, reveal the formation of a variety of ionic aggregates depending on the solvent composition that significantly affect the ion mobility and conductivity of the electrolyte. Mixtures containing tetrahydrothiophene-1-oxide exhibit a larger ion mobility due to a rapid exchange mechanism between solvent molecules, whereas the use of tetramethylene sulphone favors the formation of ionic aggregates due to the strong dipolar interactions between solvent molecules.

View Article and Find Full Text PDF

The antiferromagnetic structure of Yb_{3}Ga_{5}O_{12} is identified by neutron diffraction experiments below the previously known transition at T_{λ}=54  mK. The magnetic propagation vector is found to be k=(1/2,1/2,0), an unusual wave vector in the garnet structure. The associated complex magnetic structure highlights the role of exchange interactions in a nearly isotropic system dominated by dipolar interactions and finds echoes with exotic structures theoretically proposed.

View Article and Find Full Text PDF

We investigate the driven-dissipative dynamics of multilevel atomic arrays interacting via dipolar interactions at subwavelength spacings. Unlike two-level atoms in the weakly excited regime, multilevel atoms can become strongly entangled. The entanglement manifests as the growth of spin waves in the ground-state manifold and survives after turning off the drive.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!