Study for luminescence performance of three methyl xanthine derivatives.

Spectrochim Acta A Mol Biomol Spectrosc

Institute of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, PR China.

Published: September 2005

In this paper, the low-temperature phosphorescence (LTP), the low-temperature fluorescence (LTF), the paper substrate room-temperature phosphorescence (PS-RTP) and the room fluorescence (RTF) properties of caffeine (CF), theophylline (TP), and theobromine (TB) are investigated and compared, and some rules are found out: their maximal excitation wavelength and emission wavelength are in the range of 270-300 nm and 395-445 nm, respectively. And the PS-RTP characters of lifetime, polarization and quanta yield are also investigated and compared. It is found that their lifetimes of PS-RTP are all in the level of 0.1s. They belong to long-life phosphorescence and their PS-RTP spectra are incompletely polarized.

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http://dx.doi.org/10.1016/j.saa.2004.09.024DOI Listing

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