Pd-catalyzed Suzuki and Stille cross-couplings of aryl bromides and chlorides were carried out in quaternary ammonium salts as solvents under mild conditions and with the recycling of the catalyst.
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http://dx.doi.org/10.1021/jo050801q | DOI Listing |
J Org Chem
January 2025
Laboratory of Bioorganic Chemistry and Chemical Biology, Center for Nanotechnology, Heisenbergstrasse 11, 48149 Münster, Germany.
Xanthine nucleosides play a significant role in the expansion of the four-letter genetic code. Herein, 7-functionalized 8-aza-7-deazaxanthine ribo- and 2'-deoxyribonucleosides are described. 2-Amino-6-alkoxy nucleosides were converted to halogenated 8-aza-7-deazaxanthine nucleosides by deamination followed by hydroxy/alkoxy substitution.
View Article and Find Full Text PDFOrg Lett
December 2024
School of Chemical Sciences, University of Chinese Academy of Sciences, Beijing 101408, China.
An isomerized bithiazole imide (iBTzI) acceptor was effectively synthesized and functionalized via Suzuki or Stille coupling reactions. Compared with the isomerized bithiophene imide (iBTI) and bithiazole imide (BTzI), iBTzI has a more planar skeleton. Furthermore, the conjugated skeleton of iBTzI can be extended by hydrogen and chalcogen bonds.
View Article and Find Full Text PDFAcc Chem Res
December 2024
College of Textiles & Clothing, State Key Laboratory of Bio-fibers and Eco-textiles, Qingdao University, Qingdao 266071, China.
Sci Rep
April 2024
Takin Shimi Sepanta Industries Co, Sirvan Industrial Zone, PO 6958140120, Ilam, Iran.
The palladium anchored to BisPyP@bilayer-SiO@NMP organic-inorganic hybrid was employed as an effective and recyclable organometallic catalyst in Suzuki and Stille C-C coupling reactions. The structure of this magnetic nanocatalyst was determined using various techniques such as SEM, TEM, FT-IR, EDS, ICP-OES, VSM, N adsorption-desorption isotherms, XRD, and TGA. In both of the mentioned coupling paths, the yields of the products were very favorable and ranged from 90 to 98%.
View Article and Find Full Text PDFMolecules
January 2024
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Bipyridine and related compounds are starting materials or precursors for a variety of valuable substances such as biologically active molecules, ligands for catalysts, photosensitizers, viologens, and supramolecular architectures. Thus, it is important to classify their synthesis methods and understand their characteristics. Representative examples include methods using homo and heterocoupling of pyridine derivatives in the presence of a catalyst.
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