The presence of amoxicillin, a widely used antibiotic, has been documented in Sewage Treatment Plant (STP) effluents. As for other pharmaceuticals, ozonation is proposed as a process for its abatement from these effluents. The results of ozonation experiments on amoxicillin-containing aqueous solutions indicate that ozone attack is mainly directed towards the phenolic ring of the studied molecule leading to the formation of hydroxyderivative intermediates. No direct evidences of attack on sulfur atom with sulfoxide formation are found. A kinetic investigation is carried out allowing the assessment of the kinetics of direct ozone attack and that of OH radicals to amoxicillin.
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http://dx.doi.org/10.1016/j.jhazmat.2005.03.004 | DOI Listing |
Environ Sci Technol
January 2025
School of Environmental Science and Engineering, Shanghai Engineering Research Center of Solid Waste Treatment and Resource Recovery, Shanghai Jiao Tong University, Shanghai 200240, China.
In landfill leachates containing complex dissolved organic matter (DOM), the link between individual DOM constituents and their inherent oxidizability is unclear. Here, we resolved the molecular signatures of DOM oxidized by OH/O using FT-ICR MS, thereby elucidating their oxidizability and resistance in concentrated leachates. The comprehensive gradual fragmentation of complex leachate DOM was then revealed through a modified machine-learning framework based on 43 key pathways during ozonation.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Physical Chemistry, Gdańsk University of Technology, Narutowicza 11/12, Gdańsk, 80-233, Poland.
The study investigated the degradation of 3-methoxy-1-propanol (3M1P) by OH using the M06-2X/6-311++G(d, p) level, with CCSD(T) single-point corrections. We focused on hydrogen atom abstraction from various alkyl groups within the molecule. The rate coefficient for 3M1P degradation was calculated from the sum of the rate coefficients corresponding to the removal of H-atoms from primary (-CH), secondary (-CH-), tertiary (-CH< ), and alcohol (-ΟH) groups.
View Article and Find Full Text PDFBioresour Technol
January 2025
Departament of Biochemistry and Molecular Biology, Facultad de Farmacia, University of Seville, St./Prof. García Gonzalez 2, 41012 Seville, Spain.
A circular economy process has been developed to convert polyurethane waste into biofertilizing microorganisms through a sequential chemical/biological process. The chemical phase involves the complete depolymerization of polyurethane using ozone attack, generating an aqueous extract (OLE) composed of small, bioavailable molecules such as polyols, isocyanate derivatives, and carboxylic acids. The biological phase utilizes OLE for the generation of biomass with biofertilizing functional activity through Rhodococcus pyridinivorans fermentation.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
Fujian Key Laboratory of Coastal Pollution Prevention and Control, College of the Environment & Ecology, Xiamen University, Xiamen 361102, PR China. Electronic address:
ACS Nano
October 2024
School of Advanced Fusion Studies, Department of Intelligent Semiconductor Engineering, University of Seoul, 163 Seoulsiripdaero, Dongdaemun-gu, Seoul 02504, Republic of Korea.
The increasing menace of counterfeiting and information theft underscores the urgent need for security platforms compatible with both micro- and nanoelectronics. Existing methods for anticounterfeiting labeling and cryptographic systems rely on unclonable patterns derived from the unpredictable variability of physical phenomena. However, these approaches impose limitations on the scalability of security components.
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