Highly diastereoselective Diels-Alder reactions of Baylis-Hillman adducts.

Org Lett

School of Chemistry, University of Bristol, Cantock's Close, BS8 1TS Bristol, UK.

Published: June 2005

[reaction: see text] Baylis-Hillman adducts were found to be excellent dienophiles in Diels-Alder reactions, providing essentially complete diastereocontrol (although mixtures of endo/exo isomers) with all dienes.

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Source
http://dx.doi.org/10.1021/ol050584fDOI Listing

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