[reaction: see text] The protiodesilylation of unactivated C(sp3)-SiMe2Ph bonds proceeds efficiently by treatment with tetrabutylammonium fluoride in wet DMF or THF via isolable dimethylsilanol intermediates.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC2515625PMC
http://dx.doi.org/10.1021/ol0506821DOI Listing

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