Achiral ligands dramatically enhance rate and enantioselectivity in the Rh/phosphoramidite-catalyzed hydrogenation of alpha,beta-disubstituted unsaturated acids.

Angew Chem Int Ed Engl

Department of Organic Chemistry, Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.

Published: July 2005

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http://dx.doi.org/10.1002/anie.200500784	DOI Listing

Publication Analysis

achiral ligands

ligands dramatically

dramatically enhance

enhance rate

rate enantioselectivity

enantioselectivity rh/phosphoramidite-catalyzed

rh/phosphoramidite-catalyzed hydrogenation

hydrogenation alphabeta-disubstituted

alphabeta-disubstituted unsaturated

unsaturated acids

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