AI Article Synopsis
- The study introduces new bridged allylorganosilanes as effective precursors for creating ordered mesoporous organosilica with crystal-like pore structures.
- This innovative synthesis method enables the production of mesoporous materials that contain large organic groups, which are usually difficult to purify.
- The approach enhances the ability to create periodic mesostructures in mesoporous organosilica, potentially broadening its applications in various fields.
Article Abstract
The bridged allylorganosilanes 1,4-bis(diallylethoxysilyl)benzene and 1,4-bis(triallylsilyl)benzene are presented as new precursors for the surfactant-assisted synthesis of ordered mesoporous organosilica with pore walls having crystal-like molecular-scale periodicity. This approach provides a new route to the formation of periodic mesostructures with crystal-like pore walls. The synthesis method presented is applicable to the preparation of mesoporous organosilica with bulky organic groups, the precursors of which are typically impossible to obtain in high purity.
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| http://dx.doi.org/10.1021/ja043062o | DOI Listing |
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