Total synthesis of syringalide B, a phenylpropanoid glycoside.

Carbohydr Res

Department of Chemical Biology, School of Pharmaceutical Sciences, Peking University, Health Sciences Center, Beijing 100083, PR China.

Published: July 2005

The first total synthesis of syringalide B, 2-(4-hydroxyphenyl)ethyl 4-O-[(E)-feruloyl]-beta-D-glucopyranoside, is described. The hydroxyl groups were protected with allyloxycarbonyl (Aoc) and allyl groups, which successfully prevent the migration of the feruloyl group during the deblocking procedure.

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http://dx.doi.org/10.1016/j.carres.2005.04.011DOI Listing

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