We investigate the response of two-dimensional pattern-forming systems with a broken up-down symmetry, such as chemical reactions, to spatially resonant forcing and propose related experiments. The nonlinear behavior immediately above threshold is analyzed in terms of amplitude equations suggested for a 1:2 and 1:1 ratio between the wavelength of the spatial periodic forcing and the wavelength of the pattern of the respective system. Both sets of coupled amplitude equations are derived by a perturbative method from the Lengyel-Epstein model describing a chemical reaction showing Turing patterns, which gives us the opportunity to relate the generic response scenarios to a specific pattern-forming system. The nonlinear competition between stripe patterns and distorted hexagons is explored and their range of existence, stability, and coexistence is determined. Whereas without modulations hexagonal patterns are always preferred near onset of pattern formation, single-mode solutions (stripes) are favored close to threshold for modulation amplitudes beyond some critical value. Hence distorted hexagons only occur in a finite range of the control parameter and their interval of existence shrinks to zero with increasing values of the modulation amplitude. Furthermore, depending on the modulation amplitude, the transition between stripes and distorted hexagons is either subcritical or supercritical.
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http://dx.doi.org/10.1103/PhysRevE.71.046212 | DOI Listing |
Inorg Chem
January 2025
Institute of Inorganic Chemistry, RWTH Aachen University, 52056 Aachen, Germany.
The ternary transition-metal cyanamide MnCr(NCN) was synthesized by a solid-state metathesis reaction between MnCl, CrCl, and ZnNCN. Powder X-ray diffraction reveals that MnCr(NCN) adopts an orthorhombic [NiAs]-derived structure with symmetry, featuring a hexagonally close-packed array of NCN with metal cations in 3/4 of the octahedral interstitial holes. The question of cation order was addressed via the combinatorial use of X-ray powder diffraction, neutron powder diffraction, electron diffraction, and HAADF-STEM measurements.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
National Base for International Science & Technology Cooperation, National Local Joint Engineering Laboratory for Key materials of New Energy Storage Battery, Hunan Province Key Laboratory of Electrochemical Energy Storage and Conversion, School of Chemistry, Xiangtan University, Xiangtan 411105, China.
P2-type NaMnNiO as the cathode for sodium-ion batteries, has a relatively high theoretical specific capacity, but its unstable crystal structure and undesirable phase transitions lead to rapid capacity decay. In this work, Mg-B-O coated NaMnNiO microspheres have been synthesized via a liquid-phase method based on solvothermal synthesized NaMnNiO. The Mg-B-O coating layer significantly improves the electrochemical performance, including specific capacity, rate capability, and cycle stability.
View Article and Find Full Text PDFInorg Chem
January 2025
Department of Chemistry and Nuclear Science & Engineering Center, Colorado School of Mines, Golden, Colorado 80401, United States.
Three Sm(II) dibenzo-24-crown-8 (db24c8) complexes were synthesized in anhydrous, air-free conditions via the reaction of SmI with db24c8 and tetrabutylammonium tetraphenylborate ([TBA][BPh]; where needed) in acetonitrile (CHCN), dimethoxyethane (DME), and tetrahydrofuran (THF) to yield [Sm(db24c8)(CHCN)][BPh][I]·CHCN, [Sm(db24c8)(DME)]I, and [Sm(db24c8)(THF)]I, respectively. In each case, a 10-coordinate, staggered dodecahedral (2:6:2) environment is formed around the Sm center that is completed by either two solvent molecules (CHCN or THF) or one bidentate solvent molecule (DME). Inner-sphere solvent molecules can be excluded by reacting SmI with db24c8 in 1:3 THF:toluene to yield Sm(db24c8)I.
View Article and Find Full Text PDFJ Colloid Interface Sci
April 2025
Departamento QUIPRE, Universidad de Cantabria, Avda. Los Castros 46 39005 Santander, Spain; Grupo de Nanomedicina, IDIVAL, Avda. Cardenal Herrera Oria s/n, 39011 Santander, Spain. Electronic address:
High-charge micas exhibit improved adsorption properties and are a promising alternative clay material for the engineered barrier in deep geological repositories. When combined with Eu cations, they serve as an in situ luminescent probe for tracking the physical-chemical changes occurring in this engineered barrier over the long term. Therefore, a better understanding of the local environment of the lanthanide is highly desirable to comprehend the specific behavior of these systems.
View Article and Find Full Text PDFCyborg Bionic Syst
September 2024
Chair of Robotics, Artificial Intelligence and Real-time Systems, TUM School of Computation, Information and Technology, Technical University of Munich, Munich, Germany.
The medial entorhinal cortex of rodents is known to contain grid cells that exhibit precise periodic firing patterns based on the animal's position, resulting in a distinct hexagonal pattern in space. These cells have been extensively studied due to their potential to unveil the navigational computations that occur within the mammalian brain and interesting phenomena such as so-called grid cell distortions have been observed. Previous neuronal models of grid cells assumed their firing fields were independent of environmental boundaries.
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