We report the electrochemically tuneable intramolecular hydrogen bonding interactions between a covalently linked flavin-diamidopyridine unit.
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http://dx.doi.org/10.1039/b501887k | DOI Listing |
Int J Surg
January 2025
Department of General, Visceral, and Transplant Surgery, Ludwig-Maximilians-University Munich, Germany.
Objectives: Every year, around 300 million surgeries are conducted worldwide, with an estimated 4.2 million deaths occurring within 30 days after surgery. Adequate patient education is crucial, but often falls short due to the stress patients experience before surgery.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Institute of Inorganic Chemistry, Slovak Academy of Sciences, Dúbravská cesta 9, SK-84536 Bratislava, Slovakia.
The solvent effect on the indirect J(M-P) spin-spin coupling constant in phosphine selenoether -substituted acenaphthene complexes LMCl is studied at the PP86 level of nonrelativistic and four-component relativistic density functional theory. Depending on the metal, the solvent effect can amount to as much as 50% or more of the total -value. This explains the previously found disagreement between the J(Hg-P) coupling in LHgCl, observed experimentally and calculated without considering solvent effects.
View Article and Find Full Text PDFBiomater Sci
January 2025
School of Chemistry, Chemical Engineering and Life Science, Hubei Key Laboratory of Nanomedicine for Neurodegenerative Diseases, Wuhan University of Technology, 122 Luoshi Road, Wuhan 430070, China.
To enhance the antibacterial efficacy of tildipirosin against (S.A.) infections, optimized solid lipid nanoparticles loaded with tildipirosin (SLN-TD) were developed, using docosanoic acid (DA), octadecanoic acid (OA), hexadecanoic acid (HA), and tetradecanoic acid (TA) as lipid components.
View Article and Find Full Text PDFSoft Matter
January 2025
SUPA and School of Physics and Astronomy, The University of Edinburgh, Peter Guthrie Tait Road, Edinburgh EH9 3FD, UK.
Recent theory and experiments have shown how the buildup of a high-concentration polymer layer at a one-dimensional solvent-air interface can lead to an evaporation rate that scales with time as and that is insensitive to the ambient humidity. Using phase field modelling we show that this scaling law constitutes a naturally emerging robust regime, diffusion-limited evaporation (DLE). This regime dominates the dynamical state diagram of the system, which also contains regions of constant and arrested evaporation, confirming and extending understanding of recent experimental observations and theoretical predictions.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Department of Process Engineering and Technology of Polymer and Carbon Materials, Wroclaw University of Science and Technology, Wyb. St. Wyspiańskiego 27, 50-370 Wrocław, Poland.
We investigate a continuous electrochemical pH-swing method to capture CO from a gas phase. The electrochemical cell consists of a single cation-exchange membrane (CEM) and a recirculation of a mixture of salt and phenazine-based redox-active molecules. In the absorption compartment, this solution is saturated by CO from a mixed gas phase at high pH.
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