Objectives: To evaluate the effects of water storage, thermocycling, and the incorporation of glass-fibers, on the flexural strength of veneering composites.
Methods: Veneering composites with different fillers, matrices and polymerization methods (Belleglass Kerr Inc., Orange, CA, USA; Sculpture, Pentron Inc. Wallingford CT, USA; Sinfony, 3M Espe, Seefeld, Germany; SR Adoro LC and HP, Targis, Ivoclar Vivadent, Schaan, Liechtenstein), a glass-fiber framework material (Vectris Pontic VP, Ivoclar Vivadent) and a direct restorative composite control (Tetric Ceram, Ivoclar Vivadent) were selected. For the first part of the study, 30 bar specimens (25 x 2 x 2 mm3) per material were fabricated. Ten were stored for 24 h and 10 for 14 days in water at 37 degrees C. Ten were thermocycled (3000 x; 5-50-5 degrees C). Three-point bending tests (crosshead speed: 0.5 mm/min) were performed. For the second part of the study, all veneering materials were combined with a glass-fiber framework (VP). Sixty specimens were produced for each material (25 x 4 x 2 mm3) and treated as in the first part. Three-point bend tests were performed with the reinforcing glass-fiber framework either on the tension or the compression side. Data was evaluated by ANOVA and Weibull analysis.
Results: A decrease in flexural strength was observed after water storage or thermocycling for all veneering materials tested. None of the tested materials exhibited significant advantages compared to the control. The flexural strength of glass-fiber reinforced frameworks was ten times higher and not influenced by water storage or thermocycling. A significant reinforcing effect from glass fibers was observed when they were placed on the tension but not when placed on the compression side.
Significance: A glass-fiber framework on the tension side significantly improved the flexural strength of veneering composites. There was less deterioration due to water storage and thermocycling with the glass-fiber reinforced veneering composite compared to the non-reinforced materials.
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http://dx.doi.org/10.1016/j.dental.2005.01.013 | DOI Listing |
Environ Sci Process Impacts
January 2025
Massachusetts Institute of Technology, Department of Civil and Environmental Engineering, Parsons Laboratory, 15 Vassar Street, Cambridge, Massachusetts 02139, USA.
The high salinity and organic content in oil and gas wastewaters can cause ion suppression during liquid chromatography mass spectrometry (LC/MS) analysis, diminishing the sensitivity and accuracy of measurements in available methods. This suppression is severe for low molecular weight organic compounds such as ethanolamines (, monoethanolamine (MEA), diethanolamine (DEA), triethanolamine (TEA), -methyldiethanolamine (MDEA), and ,-ethyldiethanolamine (EDEA)). Here, we deployed solid phase extraction (SPE), mixed-mode LC, triple quadrupole MS with positive electrospray ionization (ESI), and a suite of stable isotope standards (, one per target compound) to correct for ion suppression by salts and organic matter, SPE losses, and instrument variability.
View Article and Find Full Text PDFThe EFSA Panel on Food Contact Materials (FCM) assessed the safety of the recycling process NGR LSP (EU register number RECYC328). The input is hot washed and dried poly(ethylene terephthalate) (PET) flakes mainly originating from collected post-consumer PET containers, with no more than 5% PET from non-food consumer applications. The flakes are dried (step 2), melted in an extruder (step 3) and decontaminated during a melt-state polycondensation step under high temperature and vacuum (step 4).
View Article and Find Full Text PDFRSC Adv
January 2025
Department of Chemical and Materials Engineering, School of Engineering and Digital Sciences, Nazarbayev University Astana Kazakhstan
Sodium-ion batteries (SIBs) offer several advantages over traditional lithium-ion batteries, including a more uniform sodium distribution, lower-cost materials, and safer transportation options. A promising development in SIBs is the use of hard carbons as anode materials due to their low insertion voltage and larger interlayer spacing, which improve sodium-ion insertion. Traditionally, hard carbons are made from costly carbon sources, but recent advancements have focussed on using abundant bio-waste, like coffee grounds.
View Article and Find Full Text PDFRSC Adv
January 2025
Adolphe Merkle Institute, University of Fribourg 1700 Fribourg Switzerland
β-Carotene (βC), a natural carotenoid, is the most important and effective vitamin A precursor, known also for its antioxidant properties. However, its poor water solubility, chemical instability, and low bioavailability limit its effectiveness as an orally delivered functional nutrient. Nanoparticle encapsulation improves βC's bioaccessibility by enhancing its stability and solubility.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Fudan University, Laboratory of Advanced Materials, Shanghai, 200433, Shanghai, CHINA.
Tellurium (Te), with its rich valence states (-2 to +6), could endow aqueous batteries with potentially high specific capacity. However, achieving complete and stable hypervalent Te0/Te4+ electrochemistry in an aqueous environment poses significant challenges, owing to the sluggish reduction kinetics, the easy dissolution of Te4+ species, and a controversial energy storage mechanism. Herein, for the first time, we demonstrate an amorphous strategy for robust aqueous TeO2/Te electrochemistry.
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