An analytical procedure has been proposed for the determination of (226)Ra at the low femtogram per ml concentration level in mineral water samples using double focusing sector field ICP-MS (ICP-SFMS). For the pre-concentration and separation of radium from the matrix elements in water a tandem of a laboratory-prepared filter, based on MnO(2), and Eichrom "Sr-specific" resin was used. The recovery of the method was determined to be 70.5%. The limit of detection for (226)Ra determination was 0.02 fg ml(-1), including a pre-concentration factor of 10. In addition, uranium concentration and uranium isotope ratios were measured by ICP-SFMS. In several mineral water samples with a relatively high uranium content, (226)Ra concentrations were found between 0.7-15 fg ml(-1). The effective dose of the contribution was calculated using the radionuclide concentration and dose conversion factors from the World Health Organization, WHO (1993). Assuming a mineral water consumption of 2 l d(-1), a slightly higher calculated dose than the suggested limit for drinking water (0.1 mSv y(-1)) was found in some samples.
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http://dx.doi.org/10.1039/b503011k | DOI Listing |
Water Environ Res
January 2025
Agrobiology Laboratory, Institute of Agriculture, Lithuanian Research Centre for Agriculture and Forestry (LAMMC), Lithuania.
A comparative pot study was performed to assess the toxic effects of copper (Cu) and/or zinc (Zn) contaminated wastewater (WW) irrigation on the growth, physiology, and element concentration of wheat grown for two months. The treatments included irrigation with uncontaminated wastewater (WW) as control, Cu-contaminated WW (CuWW), Zn-contaminated WW (ZnWW), and Cu + Zn contaminated WW (CuZnWW) in a completely randomized design. Compared to ZnWW, irrigation with CuWW or CuZnWW had severe effects on growth, physiology, and mineral absorption by wheat.
View Article and Find Full Text PDFJ Paleolimnol
December 2024
Institute of Geography and Oeschger Center for Climate Change Research, University of Bern, Hallerstrasse 12, 3012 Bern, Switzerland.
Unlabelled: Cyanobacteria are ubiquitous aquatic organisms with a remarkable evolutionary history reaching as far as 1.9 Ga. They play a vital role in ecosystems yet also raise concerns due to their association with harmful algal blooms.
View Article and Find Full Text PDFJ Phys Chem B
January 2025
The Njord Centre, Department of Physics, University of Oslo, Sem Sælands vei 24, NO-0316 Oslo, Norway.
Water participates in countless processes on Earth, and the properties of mineral surfaces can be drastically changed in the presence of water. For example, the fracture toughness of silica glass is reduced by 25% for water-filled cracks than for dry cracks [ , , 9341-9354]. An accurate description of water is therefore essential for modeling the behavior of minerals in aqueous environments and, in particular, for modeling dynamic processes such as fracture, where the mechanical response of water may play an important role.
View Article and Find Full Text PDFSci Rep
January 2025
Technology Innovation, PT Pertamina (Persero), Jl. Raya Bekasi KM. 20 Cakung, East Jakarta, Jakarta, 13920, Republic of Indonesia.
Selective lithium recovery from a mixture of LFP-NMC spent lithium batteries presents significant challenges due to differing structures and elemental compositions of the batteries. These differences necessitate a distinct recycling pathway for each, complicating the process for the mixture. This study explored a carbothermal reduction approach combined with water leaching under atmospheric conditions to achieve a selective lithium recovery.
View Article and Find Full Text PDFBioresour Technol
January 2025
Department of Biotechnology, Faculty of Biological Science and Technology, University of Isfahan, Isfahan 81746-73441, Iran; Environmental Research Institute, University of Isfahan, Isfahan 81746-73441, Iran.
Tannin-containing sorghum grains, suitable for acetone-butanol-ethanol (ABE) production by Clostridium acetobutylicum, have required pretreatment to eliminate tannins inhibiting the strain's amylolytic activity. This study investigates biobutanol production enhancement by immobilizing enzymes on polydopamine-functionalized polyethersulfone (PES) membranes with magnetic nanoparticles for Separated Hydrolysis and Fermentation (SHF) and Simultaneous Saccharification and Fermentation (SSF) processes. After multi-stage hot water treatment, TG3 sorghum (from the third stage) was used, where the enzyme-immobilized PES membrane produced 4.
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